Hydrogen is regarded as the potential bearer of energy of the future. Solar hydrogen is the hydrogen produced using renewable energy, particularly solar energy [15,8]. The availability of water and hours of sunshine make Algeria a place of choice for solar hydrogen production. In this work, solar hydrogen production by electrolysis of water is considered. The required energy for water dissociation is supplied by a photovoltaic system. A design and operation study of a photovoltaic system has been done for three different regions in Algeria. The production potential is highly significant particularly in the south parts of this country.