Ionothermal synthesis, crystal structure, and properties of an anionic two-dimensional cadmium metal organic framework based on paddle wheel-like cluster

2011 ◽  
Vol 14 (6) ◽  
pp. 1001-1003 ◽  
Author(s):  
Bin Tan ◽  
Zai-Lai Xie ◽  
Xiao-Ying Huang ◽  
Xin-Rong Xiao
Keyword(s):  
Crystal Structure ◽  
Metal Organic Framework ◽  
Two Dimensional ◽  
Structure And Properties ◽  
Paddle Wheel ◽  
Ionothermal Synthesis ◽  
Cadmium Metal ◽  
Metal Organic ◽  
Organic Framework

A new two-dimensional cadmium metal–organic framework: poly[bis(4,7-diphenyl-1,10-phenanthroline)(μ3-5-nitroisophthalato)cadmium(II)]

2012 ◽  
Vol 68 (11) ◽  
pp. m306-m308
Author(s):  
Jun-Wei Ye ◽  
Li-Mei Zhao ◽  
Wei Li ◽  
Gui-Ling Ning
Keyword(s):  
Building Block ◽  
General Position ◽  
Metal Organic Framework ◽  
Building Blocks ◽  
Two Dimensional ◽  
Aromatic Rings ◽  
Molecular Building Block ◽  
Cadmium Metal ◽  
Metal Organic ◽  
Organic Framework

In the title cadmium metal–organic framework complex, [Cd(C8H3NO6)(C24H16N2)]nor [Cd(NIPH)(dpphen)] (NIPH is nitroisophthalate and dpphen is 4,7-diphenyl-1,10-phenanthroline), the unique CdIIcation in a general position is coordinated by four carboxy O atoms from three symmetry-related NIPH anions and two N atoms from a dpphen ligand. The CdIIcations are bridged by pairs of NIPH anions to generate a dinuclear molecular building block, [Cd2N4(CO2R)4], with a Cd...Cd separation of 4.0936 (10) Å. Each such building block is connected to four adjacent dinuclear building blocks by NIPH anions, resulting in a two-dimensional layer framework in thebcplane. The dpphen ligands occupy the space between these layers and are linked by π–π interactions, with a separation of 3.4541 (6) Å between the central aromatic rings of inversion-related dpphen ligands. The thermogravimetric and photoluminescent properties of the complex have also been investigated.

Synthesis, structure and properties of a two-dimensional iron(II) metal-organic framework

2012 ◽  
Vol 37 (5) ◽  
pp. 463-468 ◽  
Author(s):  
Mansheng Chen ◽  
Julan Zeng ◽  
Yifang Deng ◽  
Chunhua Zhang ◽  
Zhimin Chen ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Two Dimensional ◽  
Structure And Properties ◽  
Metal Organic ◽  
Organic Framework

A flexible two-dimensional layered metal–organic framework functionalized with (trifluoromethyl)trifluoroborate: synthesis, crystal structure, and adsorption/separation properties

2020 ◽  
Vol 49 (12) ◽  
pp. 3692-3699 ◽  
Author(s):  
Atsushi Kondo ◽  
Hiroshi Kajiro ◽  
Tomohiro Nakagawa ◽  
Hideki Tanaka ◽  
Hirofumi Kanoh
Keyword(s):  
Crystal Structure ◽  
Metal Organic Framework ◽  
Adsorption Properties ◽  
Two Dimensional ◽  
Metal Organic ◽  
Organic Framework

A two-dimensional layered metal–organic framework functionalized with (trifluoromethyl)trifluoroborate (ELM-13) shows gate-type adsorption properties and good CO2 selectivity from a CO2/N2 mixture at 273 K.

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