scholarly journals Selectivity loss in Fischer-Tropsch synthesis: The effect of cobalt carbide formation

2021 ◽  
Vol 397 ◽  
pp. 1-12
Author(s):  
Paul Hazemann ◽  
Dominique Decottignies ◽  
Sylvie Maury ◽  
Séverine Humbert ◽  
Frederic C. Meunier ◽  
...  
2014 ◽  
Vol 318 ◽  
pp. 193-202 ◽  
Author(s):  
M. Claeys ◽  
M.E. Dry ◽  
E. van Steen ◽  
E. du Plessis ◽  
P.J. van Berge ◽  
...  

2016 ◽  
Vol 6 (12) ◽  
pp. 4594-4600 ◽  
Author(s):  
Geunjae Kwak ◽  
Du-Eil Kim ◽  
Yong Tae Kim ◽  
Hae-Gu Park ◽  
Seok Chang Kang ◽  
...  

In Fischer–Tropsch synthesis (FTS), cobalt carbide (Co2C) is not a catalytically active material, but rather an undesired cobalt phase associated with low catalytic performance.


ACS Catalysis ◽  
2011 ◽  
Vol 1 (11) ◽  
pp. 1581-1588 ◽  
Author(s):  
Janet Chakkamadathil Mohandas ◽  
Muthu Kumaran Gnanamani ◽  
Gary Jacobs ◽  
Wenping Ma ◽  
Yaying Ji ◽  
...  

2020 ◽  
Vol 42 ◽  
pp. 227-232 ◽  
Author(s):  
Fanfei Sun ◽  
Ruoou Yang ◽  
Zhaoming Xia ◽  
Yuqi Yang ◽  
Ziang Zhao ◽  
...  

ChemCatChem ◽  
2018 ◽  
Vol 10 (6) ◽  
pp. 1300-1312 ◽  
Author(s):  
Diego Peña ◽  
Lise Jensen ◽  
Andrea Cognigni ◽  
Rune Myrstad ◽  
Thomas Neumayer ◽  
...  

Author(s):  
Phathutshedzo Rodney Khangale ◽  
Reinout Meijboom ◽  
Kalala Jalama

The effect of activating Co/Al2O3 catalyst by diluted CO or H2 on catalyst performance for Fischer-Tropsch reaction was investigated. The catalyst was prepared by incipient wetness impregnation of the support and characterized using BET N2 physisorption, SEM, and XRD analyses. The reduction behavior of the catalyst in presence of CO and H2 individually was evaluated using TPR analyses. The data reveal that CO activates Co/Al2O3 catalyst at a lower temperature than H2 and produces a catalyst with higher rate for liquid product formation. It also leads to higher methane selectivity probably due to some cobalt carbide formation. Copyright © 2019 BCREC Group. All rights reservedReceived: 9th April 2018; Revised: 21st August 2018; Accepted: 27th August 2018; Available online: 25th January 2019; Published regularly: April 2019How to Cite: Khangale, P.R., Meijboom, R., Jalama, K. (2019). Fischer-Tropsch Synthesis over Unpromoted Co/ɣ-Al2O3 Catalyst: Effect of Activation with CO Compared to H2 on Catalyst Performance. Bulletin of Chemical Reaction Engineering & Catalysis, 14 (1): 35-41 (doi:10.9767/bcrec.14.1.2519.35-41)Permalink/DOI: https://doi.org/10.9767/bcrec.14.1.2519.35-41 


2016 ◽  
Vol 261 ◽  
pp. 40-47 ◽  
Author(s):  
Muthu Kumaran Gnanamani ◽  
Gary Jacobs ◽  
Uschi M. Graham ◽  
Mauro C. Ribeiro ◽  
Fabio B. Noronha ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document