Synthesis and characterization of fluorine–thiophene-based π-conjugated polymers using coupling reaction

We report a pyridine-flanked diketopyrrolopyrrole monomer and all-acceptor conjugated polymers synthesized therefrom. Photophysical, thermal and electrochemical properties of the polymers have been determined.

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Synthesis and Characterization of New Luminescent 1,10-Phenanthroline- and Pyridine-Containing π-Conjugated Polymers. Their Optical Response to Protic Acid, Mn+, and Solvents

Macromolecules ◽

10.1021/ma030280d ◽

2003 ◽

Vol 36 (20) ◽

pp. 7513-7519 ◽

Cited By ~ 69

Author(s):

Takuma Yasuda ◽

Takakazu Yamamoto

Keyword(s):

Conjugated Polymers ◽

Optical Response ◽

Synthesis And Characterization

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Synthesis and Characterization of Novel PEPPSI type Pd–BICAAC Complexes

10.26434/chemrxiv-2022-0m443 ◽

2022 ◽

Author(s):

Márton Nagyházi ◽

Balázs Almási ◽

Ádám Lukács ◽

Attila Bényei ◽

Tibor Nagy ◽

...

Keyword(s):

High Activity ◽

Coupling Reaction ◽

Kinetic Studies ◽

Elemental Mercury ◽

Palladium Complexes ◽

Synthesis And Characterization ◽

Heck Coupling ◽

Moisture Resistant

A series of bicyclic alkylamino carbenes (BICAAC) (where N-aryl = dipp, mes, 2,6-dimethyl-4-(dimethylamino)phenyl, 5a-d) and their novel air- and moisture-resistant pyridine (pyridine, 4 dimethylaminopyridine) containing palladium PEPPSI-type Pd(II) complexes (6a-e) were synthetized and characterized. The new palladium complexes have shown high activity in Mizoroki–Heck coupling reaction even at as low as 100 ppm loading (TON up to 10000). Kinetic studies revealed that reactions carried out in the presence of elemental mercury resulted in decrease in activity. It indicates that the coupling reaction may have both molecular and Pd(0)-mediated catalytic paths.

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Synthesis and characterization of novel π-conjugated polymers with phosphole ring derivatives

Journal of Polymer Science Part A Polymer Chemistry ◽

10.1002/pola.22043 ◽

2007 ◽

Vol 45 (14) ◽

pp. 2867-2875 ◽

Cited By ~ 19

Author(s):

Hai-Sub Na ◽

Yasuhiro Morisaki ◽

Yasuhiro Aiki ◽

Yoshiki Chujo

Keyword(s):

Conjugated Polymers ◽

Synthesis And Characterization

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Conductive Polymers Based on Phenothiazine-Benzothiadiazole: Synthesis, Characterization of Photovoltaics

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.634-638.2643 ◽

2013 ◽

Vol 634-638 ◽

pp. 2643-2650 ◽

Cited By ~ 3

Author(s):

Dae Hee Yun ◽

Han Sol Yoo ◽

Tae Won Ko ◽

Yong Sung Park ◽

Je Wan Woo

Keyword(s):

Conjugated Polymers ◽

Power Conversion ◽

Coupling Reaction ◽

Band Gap Energy ◽

Suzuki Coupling Reaction ◽

Gap Energy ◽

Solution State ◽

Conversion Efficiencies ◽

Film State

Two new π-conjugated polymers (Poly[(N-10’-(octan-3-yl)-phenothiazin-3,7-ylene)-alt- (4’,7’-bis(thiophen-2-yl)benzo[c][1,2,5]thiadiazole)] (PoPTZ-BT-BTD), Poly[(N-10`-(octan-3-yl) -phenothiazin-3,7-ylene)-alt-(4’,7’-bis(thiophen-2-yl)-5,6-bis(octyloxy)benzo[c][1,2,5]thiadiazole)] (PoPTZ-BT-BoBTD) ) were synthesized through the Suzuki coupling reaction for organic photovoltaics (OPVs), and their optical and electrochemical properties were analyzed. Their wavelength of maximun absorption was 526 nm and 506 nm in solution state, repectively, and 560 nm and 522 nm in film state, respectively. Their band-gap energy was 2.01 eV and 2.09 eV in solution state, and 1.82 eV and 1.91 eV in film state, respectively. The results of analysis of the chrateristics of photovoltaics, 0.79 % and 0.99 % of the maximum power conversion efficiencies (PCE), repectively.

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