Broadband frequency conversion of ultrashort pulses using high-Q metasurface cavities

Frequency conversion of light can be dramatically enhanced using high quality factor (Q-factor) cavities. Unfortunately, the achievable conversion efficiencies and conversion bandwidths are fundamentally limited by the time–bandwidth limit of the cavity, restricting their use in frequency conversion of ultrashort pulses. Here, we propose and numerically demonstrate sum-frequency generation based frequency conversion using a metasurface-based cavity configuration that could overcome this limitation. The proposed experimental configuration takes use of the spatially dispersive responses of periodic metasurfaces supporting collective surface lattice resonances (SLRs), and can be utilized for broadband frequency conversion of ultrashort pulses. We investigate a plasmonic metasurface, supporting a high-Q SLR (Q=500, linewidth of 2 nm) centred near 1000 nm, and demonstrate ~1000-fold enhancements of nonlinear signals. Furthermore, we demonstrate broadband frequency conversion with a pump conversion bandwidth reaching 75 nm, a value that greatly surpasses the linewidth of the studied cavity. Our work opens new avenues to utilize high-Q metasurfaces also for broadband frequency conversion of light.

Amidinium additives for high-performance perovskite solar cells

Perovskite solar cells (PSCs) have developed rapidly and achieved power conversion efficiencies (PCE) of over 25% with diverse technical routes. However, defect is a major factor for device degradation, so...

Understanding and suppressing non-radiative losses in methylammonium-free wide-bandgap perovskite solar cells

With power conversion efficiencies of perovskite-on-silicon and all-perovskite tandem solar cells increasing at rapid pace, wide bandgap (> 1.7 eV) metal-halide perovskites (MHPs) are becoming a major focus of academic...

Impact of Mode-Area Dispersion on Nonlinear Pulse Propagation in Gas-Filled Anti-Resonant Hollow-Core Fiber

We numerically investigate the effect of mode-area dispersion in a tubular-type anti-resonant hollow-core fiber by using a modified generalized nonlinear Schrödinger equation that takes into account the wavelength-dependent mode area in its nonlinear term. The pulse evolution dynamics with and without the effect of mode-area dispersion are compared and analyzed. We show that strong dispersion of the mode area in the proximity of the cladding wall thickness-induced resonances has a significant impact on the soliton pulse propagation, resulting in considerable changes in the conversion efficiencies in nonlinear frequency mixing processes. The differences become more prominent when the pump has higher energy and is nearer to a resonance. Hence, the mode-area dispersion must be accounted for when modeling such a case.

Kesterite Cu2ZnSnS4-xSex Thin Film Solar Cells

Kesterite Cu2ZnSnS4-xSex (CZTS) is a promising thin film photovoltaic (PV) material with low cost and nontoxic constitute as well as decent PV properties, being regarded as a PV technology that is truly compatible with terawatt deployment. The kesterite CZTS thin film solar cell has experienced impressive development since its first report in 1996 with power conversion efficiencies (PCEs) of only 0.66% to current highest value of 13.0%, while the understanding of the material, device physics, and loss mechanism is increasingly demanded. This chapter will review the development history of kesterite technology, present the basic material properties, and summarize the loss mechanism and strategies to tackle these problems to date. This chapter will help researchers have brief background knowledge of kesterite CZTS technology and understand the future direction to further propel this new technology forward.

Heat to Hydrogen by RED—Reviewing Membranes and Salts for the RED Heat Engine Concept

The Reverse electrodialysis heat engine (REDHE) combines a reverse electrodialysis stack for power generation with a thermal regeneration unit to restore the concentration difference of the salt solutions. Current approaches for converting low-temperature waste heat to electricity with REDHE have not yielded conversion efficiencies and profits that would allow for the industrialization of the technology. This review explores the concept of Heat-to-Hydrogen with REDHEs and maps crucial developments toward industrialization. We discuss current advances in membrane development that are vital for the breakthrough of the RED Heat Engine. In addition, the choice of salt is a crucial factor that has not received enough attention in the field. Based on ion properties relevant for both the transport through IEMs and the feasibility for regeneration, we pinpoint the most promising salts for use in REDHE, which we find to be KNO3, LiNO3, LiBr and LiCl. To further validate these results and compare the system performance with different salts, there is a demand for a comprehensive thermodynamic model of the REDHE that considers all its units. Guided by such a model, experimental studies can be designed to utilize the most favorable process conditions (e.g., salt solutions).

Efficient and Stable Perovskite Solar Cells Based on Inorganic Hole Transport Materials

Although power conversion efficiencies of organic-inorganic lead halide perovskite solar cells (PSCs) are approaching those of single-crystal silicon solar cells, the working device stability due to internal and external factors, such as light, temperature, and moisture, is still a key issue to address. The current world-record efficiency of PSCs is based on organic hole transport materials, which are usually susceptible to degradation from heat and diffusion of dopants. A simple solution would be to replace the generally used organic hole transport layers (HTLs) with a more stable inorganic material. This review article summarizes recent contributions of inorganic hole transport materials to PSC development, focusing on aspects of device performance and long-term stability. Future research directions of inorganic HTLs in the progress of PSC research and challenges still remaining will also be discussed.

Design of a High Efficiency High Step-Up/Step-Down Bidirectional Isolated DC–DC Converter

This paper presents a novel bidirectional DC–DC converter, equipped with a three-winding coupled inductor, that can be applied to high-voltage, bidirectional DC–DC energy conversion and meet battery charging and discharging requirements. The architecture consists of a semi-Z-source converter and a forward–flyback converter featuring a three-winding coupled inductor with an iron core. This proposed topology retains the current continuity characteristics of the low-voltage side, all switches possess the zero-voltage switching feature, and the switches on the low-voltage side in the step-down mode have a synchronous rectification function. A 500-W bidirectional converter is implemented to examine the practicality and feasibility of the proposed topology. The relatively streamlined design of the converter can greatly reduce production costs. In the step-up and step-down modes, the maximum energy conversion efficiencies are 95.74% and 96.13%, respectively.

In-situ ellipsometry measurements on the phase segregation of mixed halide lead perovskites

Mixed halide lead perovskite such as methylammonium lead iodide bromides MAPb(BrxI1-x)3 have emerged as one of the most promising materials of future solar cells, offering high power conversion efficiencies and bandgap tunability. Among other factors, the reversible phase segregation under even low light intensities is still limiting their potential use. During this process, the material segregates locally into iodide-rich and bromide-rich phases, lowering the effective bandgap energy. While several studies have been done to illuminate the mechanism and suppression of phase segregation, fundamental aspects remain unclear. Phase compositions after segregation vary extensively between different studies and the exact amounts of phases often remain unmentioned. For iodide-rich phases, the end-point compositions at around x=0.2 are widely accepted but the proportion of the phase is difficult to measure. In this report, we observe the phase segregation using spectroscopic ellipsometry, a powerful, nondestructive technique that has been employed in the study of film degradation before. We obtained dynamic ellipsometric measurements from x=0.5 mixed halide lead perovskite thin films protected by a polystyrene layer under green laser light with a power density of ~11 W/cm2. Changes in the bandgap region can be correlated to the changes in composition caused by phase segregation, allowing for the kinetics to be observed. Time constants between 1.7(± 0.7)×10-3 s-1 for the segregation and 1.5(± 0.6)×10-4 s-1 for recovery were calculated. We expect ellipsometry to serve as a complementary technique to other spectroscopies in studying mixed-halide lead perovskites phase segregation in the future.

Compact and High-Efficiency Rectenna for Wireless Power-Harvesting Applications

A compact, single-layer microstrip rectenna for dedicated far-field RF wireless power-harvesting applications is presented. The proposed rectenna circuit configurations including multiband triple L-Arms patch antenna with diamond slot ground are designed to resonate at 10, 13, 17, and 26 GHz with 10 dB impedance bandwidths of 0.67, 0.8, 2.45, and 4.3 GHz, respectively. Two rectifier designs have been fabricated and compared, a half wave rectifier with a shunted Schottky diode and a voltage doubler rectifier. The measured and simulated maximum conversion efficiencies of the rectifier using the shunted diode half-wave rectifier are 41%, and 34%, respectively, for 300 Ω load resistance, whereas they amount to 50% and 43%, respectively, for voltage doubler rectifier with 650 Ω load resistance. Compared to the shunted rectifier circuit, it is significant to note that the voltage doubler rectifier circuit has higher efficiency. Both rectifier’s circuits presented are tuned for a center frequency of 10 GHz and implemented using 0.81 mm thick Rogers (RO4003c) substrate. The overall size of the antenna is 16.5 × 16.5 mm2, and the shunted rectifier is only 13.3 × 8.2 mm2 and 19.7 × 7.4 mm2 for the voltage doubler rectifier. The antenna is designed and simulated using the CST Microwave Studio Suite (Computer Simulation Technology), while the complete rectenna is simulated using Agilent’s ADS tool with good agreement for both simulation and measurements.