Cation distribution dependence of magnetic properties of sol–gel prepared MnFe2O4 spinel ferrite nanoparticles

2010 ◽  
Vol 322 (21) ◽  
pp. 3396-3400 ◽  
Author(s):  
Jianjun Li ◽  
Hongming Yuan ◽  
Guodong Li ◽  
Yanju Liu ◽  
Jinsong Leng
2016 ◽  
Vol 399 ◽  
pp. 109-117 ◽  
Author(s):  
Raghvendra Singh Yadav ◽  
Jaromir Havlica ◽  
Jiri Masilko ◽  
Lukas Kalina ◽  
Jaromir Wasserbauer ◽  
...  

2015 ◽  
Vol 378 ◽  
pp. 190-199 ◽  
Author(s):  
Raghvendra Singh Yadav ◽  
Jaromir Havlica ◽  
Miroslav Hnatko ◽  
Pavol Šajgalík ◽  
Cigáň Alexander ◽  
...  

2007 ◽  
Vol 21 (05) ◽  
pp. 723-729 ◽  
Author(s):  
JUN WANG ◽  
YEJUN WU ◽  
YUEJIN ZHU

Nanoparticles of MnFe 2 O 4 have been synthesized under an induced magnetic field by a hydrothermal process. A strong correlation between the cation distribution and the magnetic properties of MnFe 2 O 4 nanoparticles has been identified. From the results of Mössbauer spectroscopy it has been found that the nanoparticles synthesized under zero magnetic fields have 21% inversion occupancy in the tetrahedral sites by Fe 3+ cations, while this value decreases to 10% in the sample formed under a 0.25 T magnetic field. The results explain well the decrease in saturation magnetization from 62.2 emu/g to 52.8 emu/g for the sample formed under a magnetic field. This provides an understanding on how to control the inner structure in order to control the magnetic properties of these spinel ferrite nanoparticles.


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