In situ generation of highly active olefin metathesis initiators

2006 ◽  
Vol 691 (24-25) ◽  
pp. 5482-5486 ◽  
Author(s):  
Nele Ledoux ◽  
Bart Allaert ◽  
David Schaubroeck ◽  
Stijn Monsaert ◽  
Renata Drozdzak ◽  
...  
Keyword(s):  
Olefin Metathesis ◽  
Highly Active ◽  
In Situ Generation

scholarly journals Stereoretentive Olefin Metathesis Made Easy: In Situ Generation of Highly Selective Ruthenium Catalysts from Commercial Starting Materials

2018 ◽  
Vol 20 (21) ◽  
pp. 6822-6826 ◽  
Author(s):  
Daniel S. Müller ◽  
Idriss Curbet ◽  
Yann Raoul ◽  
Jérôme Le Nôtre ◽  
Olivier Baslé ◽  
...  
Keyword(s):  
Olefin Metathesis ◽  
Ruthenium Catalysts ◽  
In Situ Generation

Facile in situ generation of highly active (arylimido)vanadium(v)–alkylidene catalysts for the ring-opening metathesis polymerization (ROMP) of cyclic olefins by immediate phenoxy ligand exchange

2018 ◽  
Vol 54 (96) ◽  
pp. 13559-13562 ◽  
Author(s):  
Hitomi Hayashibara ◽  
Xiaohua Hou ◽  
Kotohiro Nomura
Keyword(s):  
Ligand Exchange ◽  
Ring Opening ◽  
Ring Opening Metathesis Polymerization ◽  
Metathesis Polymerization ◽  
Cyclic Olefins ◽  
Highly Active ◽  
In Situ Generation

Remarkably active vanadium(v)–alkylidene catalysts for the ring-opening metathesis polymerization of cyclic olefins can be generated in situ upon addition of C6F5OH or C6Cl5OH.

Evidences of the in situ generation of highly active Lewis acid species on Zr-SBA-15

2009 ◽  
Vol 371 (1-2) ◽  
pp. 85-91 ◽  
Author(s):  
Maria D. Gracia ◽  
Alina M. Balu ◽  
Juan M. Campelo ◽  
Rafael Luque ◽  
Jose M. Marinas ◽  
...  
Keyword(s):  
Lewis Acid ◽  
Highly Active ◽  
In Situ Generation
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