Naphthyl C8-H hydrogen activation and synthesis of organometallic ruthenium complex: Crystal structure of hydride intermediates and catalytic transfer hydrogenation

2019 ◽  
Vol 880 ◽  
pp. 91-97 ◽  
Author(s):  
Manju Bala ◽  
Anand Ratnam ◽  
Rajan Kumar ◽  
Kaushik Ghosh
Keyword(s):  
Crystal Structure ◽  
Ruthenium Complex ◽  
Transfer Hydrogenation ◽  
Catalytic Transfer Hydrogenation ◽  
Hydrogen Activation ◽  
Complex Crystal Structure ◽  
Catalytic Transfer ◽  
Complex Crystal

A Novel Example of Metal-Mediated Aromatic Thiolation in a Ruthenium Complex. Crystal Structure of RuII(SC6H4NNC6H4N)2†

1996 ◽  
Vol 35 (10) ◽  
pp. 3050-3052 ◽  
Author(s):  
Bidyut Kumar Santra ◽  
Ganesh A. Thakur ◽  
Prasanta Ghosh ◽  
Amitava Pramanik ◽  
Goutam Kumar Lahiri
Keyword(s):  
Crystal Structure ◽  
Ruthenium Complex ◽  
Complex Crystal Structure ◽  
Complex Crystal

scholarly journals Dual utility of a single diphosphine–ruthenium complex: a precursor for new complexes and, a pre-catalyst for transfer-hydrogenation and Oppenauer oxidation

RSC Advances ◽  
2021 ◽  
Vol 11 (26) ◽  
pp. 15617-15631
Author(s):  
Aparajita Mukherjee ◽  
Samaresh Bhattacharya
Keyword(s):  
Ruthenium Complex ◽  
Transfer Hydrogenation ◽  
Catalytic Transfer Hydrogenation ◽  
Catalytic Transfer ◽  
Oppenauer Oxidation

The [Ru(dppbz)(CO)2Cl2] (dppbz = 1,2-bis(diphenylphosphino)benzene) complex serves as an useful precursor for the synthesis of new complexes, and also as an efficient pre-catalyst for catalytic transfer-hydrogenation and Oppenauer oxidation.

A mixed chloride/trifluoromethanesulfonate ligand species in a ruthenium(II) complex

2013 ◽  
Vol 69 (8) ◽  
pp. 859-861 ◽  
Author(s):  
Gustavo Santiso-Quinones ◽  
Rafael E. Rodriguez-Lugo
Keyword(s):  
Crystal Structure ◽  
Mixed Ligand ◽  
Transfer Hydrogenation ◽  
Spectroscopic Methods ◽  
Catalytic Transfer Hydrogenation ◽  
Anionic Ligands ◽  
Chloride Ligand ◽  
Catalytic Transfer ◽  
Ligand Species

The compound [2-(aminomethyl)pyridine-κ2N,N′][chlorido/trifluoromethanesulfonato(0.91/0.09)][(10,11-η)-5H-dibenzo[a,d]cyclohepten-5-amine-κN](triphenylphosphane-κP)ruthenium(II) trifluoromethanesulfonate dichloromethane 0.91-solvate, [Ru(CF3SO3)0.09Cl0.91(C6H8N2)(C15H13N)(C18H15P)]CF3SO3·0.91CH2Cl2, belongs to a series of RuIIcomplexes that had been tested for transfer hydrogenation, hydrogenation of polar bonds and catalytic transfer hydrogenation. The crystal structure determination of this complex revealed disorder in the form of two different anionic ligands sharing the same coordination site, which other spectroscopic methods failed to characterize. The reduced catalytic activity of the title compound was not fully understood until the crystallographic data provided evidence for the mixed ligand species. The crystal structure clearly shows that the majority of the synthesized material has a chloride ligand present. Only a small portion of the material is the expected complex [RuII(OTf)(ampy)(η2-tropNH2)(PPh3)]OTf, where OTf is triflate or trifluoromethanesulfonate, ampy is 2-(aminomethyl)pyridine and tropNH2is 5H-dibenzo[a,d]cyclohepten-5-amine.

Ruthenium complex based on [N,N,O] tridentate -2-ferrocenyl-2-thiazoline ligand for catalytic transfer hydrogenation

2021 ◽  
Vol 932 ◽  
pp. 121630
Author(s):  
J I Badillo-Gómez ◽  
E P Sánchez-Rodríguez ◽  
R A Toscano ◽  
M Gouygou ◽  
M C Ortega-Alfaro ◽  
...  
Keyword(s):  
Ruthenium Complex ◽  
Transfer Hydrogenation ◽  
Catalytic Transfer Hydrogenation ◽  
Catalytic Transfer

Ruthenium (ii) complexes with c- and c-symmetric bis-(+)-camphopyrazole ligands and their evaluation in catalytic transfer hydrogenation of aldehydes

2021 ◽  
pp. 120429
Author(s):  
Christian O. Blanco ◽  
Ligia Llovera ◽  
Alberto Herrera ◽  
Romano Dorta ◽  
Giuseppe Agrifoglio ◽  
...  
Keyword(s):  
Transfer Hydrogenation ◽  
Catalytic Transfer Hydrogenation ◽  
Catalytic Transfer

Influence of metal oxide and heteropoly tungustate location in mesoporous silica towards catalytic transfer hydrogenation of furfural to γ-valerolactone

2021 ◽  
Author(s):  
Bolla Srinivasarao ◽  
Yogita Y ◽  
Dhana Lakshmi Darsi ◽  
Krishna Kumari Pamula ◽  
N. Lingaiah
Keyword(s):  
Mesoporous Silica ◽  
Metal Oxide ◽  
Transfer Hydrogenation ◽  
Catalytic Transfer Hydrogenation ◽  
One Pot ◽  
Catalytic Transfer

One pot conversion of furfural to -valerolactone by transfer hydrogenation has been achieved over bifunctional Zr and TPA located in mesoporous silica catalysts. Different catalysts with TPA and ZrO2 located...

Synergistic Effect of B and N Dopants in Catalytic Transfer Hydrogenation

2018 ◽  
Vol 7 (6) ◽  
pp. 1107-1112 ◽  
Author(s):  
Yunrui Zhang ◽  
Yingying Zhai ◽  
Minzhe Chu ◽  
Li Huo ◽  
Haijun Wang ◽  
...  
Keyword(s):  
Synergistic Effect ◽  
Transfer Hydrogenation ◽  
Catalytic Transfer Hydrogenation ◽  
Catalytic Transfer
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