Leveraging chemical actinometry and optical radiometry to reduce uncertainty in photochemical research

Author(s):  
Emily Asenath-Smith ◽  
Emma K. Ambrogi ◽  
Lee C. Moores ◽  
Stephen D. Newman ◽  
Jonathon A. Brame
Keyword(s):  
2020 ◽  
Vol 12 (9) ◽  
pp. 1454
Author(s):  
Xiaobing Zheng ◽  
Maopeng Xia ◽  
Wenchao Zhai ◽  
Youbo Hu ◽  
Jianjun Li ◽  
...  

We propose a space benchmark sensor with onboard SI (Système International) traceability by means of quantum optical radiometry. Correlated photon pairs generated by spontaneous parametric down-conversion (SPDC) in nonlinear crystals are used to calibrate the absolute responsivity of a solar observing radiometer. The calibration is systematic, insensitive to degradation and independent of external radiometric standards. Solar spectral irradiance at 380–2500 nm is traceable to the photon rate and Planck’s constant with an expected uncertainty of about 0.35%. The principle of SPDC calibration and a prototype design of the solar radiometer are introduced. The uncertainty budget is analyzed in consideration of errors arising from calibration and observation modes.


Sign in / Sign up

Export Citation Format

Share Document