Nucleophilic trifluormethylation of aryl boronic acid under heterogeneous Cu(INA) 2 catalysis at room temperature: The catalytic copper-based protocol

The first room-temperature Suzuki–Miyaura coupling of aryl-boronic acid with aryl chlorides catalyzed by a Pd(OAc)2/NiXantphos-based system is communicated.

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Green synthesis of biphenyl carboxylic acids via Suzuki–Miyaura cross-coupling catalyzed by a water-soluble fullerene-supported PdCl2 nanocatalyst

Journal of Chemical Research ◽

10.1177/1747519819836505 ◽

2019 ◽

Vol 43 (1-2) ◽

pp. 50-52

Author(s):

Wanyun Liu ◽

Xiuming Zhou ◽

Ping Huo ◽

Jingbo Li ◽

Guangquan Mei

Keyword(s):

Green Synthesis ◽

Carboxylic Acids ◽

Boronic Acid ◽

Room Temperature ◽

Cross Coupling ◽

Water Soluble ◽

Aryl Boronic Acid

A green synthesis of variously substituted biphenyl carboxylic acids was achieved through Suzuki–Miyaura cross-coupling of a bromobenzoic acid with an aryl boronic acid using a water-soluble fullerene-supported PdCl2 nanocatalyst (C60-TEGs/PdCl2). Yields of more than 90% were obtained at room temperature in 4 h using 0.05 mol% catalyst and 2 equiv. K2CO3.

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Sequential catalysis: exploiting a single rhodium(i) catalyst to promote an alkyne hydroacylation–aryl boronic acid conjugate addition sequence

Chemical Science ◽

10.1039/c6sc03066a ◽

2017 ◽

Vol 8 (1) ◽

pp. 536-540 ◽

Cited By ~ 11

Author(s):

Maitane Fernández ◽

Matthias Castaing ◽

Michael C. Willis

Keyword(s):

Boronic Acid ◽

Conjugate Addition ◽

Controlled Assembly ◽

Bond Forming ◽

Bond Forming Reactions ◽

Acid Conjugate ◽

Aryl Boronic Acid

We demonstrate that a single Rh(i) complex can promote two mechanistically distinct C–C bond-forming reactions – alkyne hydroacylation and aryl boronic acid conjugate addition – to deliver substituted ketone products from the controlled assembly of three readily available fragments.

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Influence of length and structure of aryl boronic acid crosslinkers on organogels with partially hydrolyzed poly(vinyl acetate)

Colloid & Polymer Science ◽

10.1007/s00396-018-4326-7 ◽

2018 ◽

Vol 296 (6) ◽

pp. 1047-1056 ◽

Cited By ~ 4

Author(s):

Teresa T. Duncan ◽

Richard G. Weiss

Keyword(s):

Vinyl Acetate ◽

Boronic Acid ◽

Aryl Boronic Acid

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Mechanism of Cu-Catalyzed Aryl Boronic Acid Halodeboronation Using Electrophilic Halogen: Development of a Base-Catalyzed Iododeboronation for Radiolabeling Applications

Organic Letters ◽

10.1021/acs.orglett.9b00942 ◽

2019 ◽

Vol 21 (7) ◽

pp. 2488-2492 ◽

Cited By ~ 7

Author(s):

John J. Molloy ◽

Kerry M. O’Rourke ◽

Carolina P. Frias ◽

Nikki L. Sloan ◽

Matthew J. West ◽

...

Keyword(s):

Boronic Acid ◽

Aryl Boronic Acid

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Copper(ii)-catalyzed protoboration of allenes in aqueous media and open air

New Journal of Chemistry ◽

10.1039/d0nj02010a ◽

2021 ◽

Author(s):

Russell F. Snead ◽

Jan Nekvinda ◽

Webster L. Santos

Keyword(s):

Boronic Acid ◽

Room Temperature ◽

Aqueous Media ◽

Boronic Acid Derivatives

A copper(ii)-catalyzed internal protoboration of monosubstituted allenes efficiently occurs in water at room temperature and open air to generate 1,1-disubstituted vinyl boronic acid derivatives.

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