Matrix isolation FT-IR, FT-Raman spectroscopy, conformational ab initio calculations, and vibrational frequencies of meso and racemic-2,4-pentanediol

2004 ◽  
Vol 689 (3) ◽  
pp. 183-190 ◽  
Author(s):  
Carlos E Manzanares ◽  
Dovie Reynolds ◽  
Ernest K Lewis ◽  
Craig J Moehnke ◽  
Nairmen Mina-Camilde ◽  
...  
LWT ◽  
2020 ◽  
Vol 121 ◽  
pp. 108959 ◽  
Author(s):  
Agnieszka Nawrocka ◽  
Magdalena Krekora ◽  
Zbigniew Niewiadomski ◽  
Monika Szymańska-Chargot ◽  
Ada Krawęcka ◽  
...  

2009 ◽  
Vol 40 (9) ◽  
pp. 1262-1273 ◽  
Author(s):  
C. Yohannan Panicker ◽  
Hema Tresa Varghese ◽  
K.R. Ambujakshan ◽  
Samuel Mathew ◽  
Subarna Ganguli ◽  
...  

2003 ◽  
Vol 7 (1) ◽  
pp. 51-56 ◽  
Author(s):  
Keunok Han Yu ◽  
Yang Hyun Yoo ◽  
John Moon Rhee ◽  
Myong-Hoon Lee ◽  
Soo-Chang Yu

1995 ◽  
Vol 49 (12) ◽  
pp. 1834-1840 ◽  
Author(s):  
A. Scholz ◽  
A. Wokaun

The vibrational frequencies of the N=N stretching mode of 1-aryl-3-alkyl-3-hydroxy-triazenes and their platinum complexes (PtL4; L = triazene) were investigated by FT-IR and FT-Raman spectroscopy. The influence of electron-donating or -withdrawing substituents on the phenyl ring and of different alkyl substituents at the N3 atom on these frequencies was considered. The N=N vibrational frequency is significantly lowered (as a result of the delocalization of the N=N bond over three nitrogen atoms) compared to related compounds. The Pt complexes show a reduced intensity and an increased linewidth in the vibrational spectra. Additionally, the NMR spectra of the 1-aryl-3-alkyl-3-hydroxy-triazenes were recorded in order to show the tautomeric structure of these substances. The hydroxy triazenes preferentially exist in the N1H form. As a consequence, the N=N stretching frequencies of the hydroxy triazenes appear to be influenced by the superposition of two counteracting effects, the delocalization of the N=N bond and tautomerism.


2011 ◽  
Vol 57 (2) ◽  
pp. 187-195 ◽  
Author(s):  
M.C. Gonçalves ◽  
I.C. Fernandes ◽  
J. Hümmer ◽  
V. de Zea Bermudez

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