The structure of N-allyl-(5-phenyl-[1,3,4]thiadiazol-2-yl) amine in solution and the solid state studied by the 1H, 13C, 15N NMR spectroscopy and X-ray crystallography
The first isolable molecular thorium nitride, [(NR2)3Th(μ-N)Th(NR2)3]−, was synthesized by reaction of [Th{N(R)(SiMe2)CH2}(NR2)2] with NaNH2 and characterized by X-ray crystallography, 15N NMR spectroscopy, and DFT calculations.