A 1%Ni/SBA-15(P) catalyst was synthesized with a P123-assisted impregnation method, which exhibited high CO2 conversion and stability in the reverse water-gas shift reaction. For the 1%Ni/SBA-15(P) catalyst, TEM and TPR characterizations demonstrated that the highly dispersed NiO particles at about 3 nm strongly interacted with the SiO2 support. During reverse water-gas shift reaction, the 1%Ni/SBA-15(P) catalyst exhibited higher CO2 conversion than the 1%Ni/SBA-15 catalyst prepared by the conventional impregnation method without P123. The CO2 conversion of the 1%Ni/SBA-15(P) catalyst at 700 °C was 33.7%, which was three times that of the 1%Ni/SBA-15 catalyst. Moreover, the former catalyst was stable at 700 °C within 1000 min. The good activity and stability of the 1%Ni/SBA-15(P) catalyst was owing to small Ni particles that strongly interacted with SBA-15.
Effect of Pd and Ir as Promoters in the Activity of Ni/CeZrO2 Catalyst for the Reverse Water-Gas Shift Reaction