Metal complexes of pyrimidine derived ligands – Syntheses, characterization and X-ray crystal structures of Ni(II), Co(III) and Fe(III) complexes of Schiff base ligands derived from S-methyl/S-benzyl dithiocarbazate and 2-S-methylmercapto-6-methylpyrimidine-4-carbaldehyde

Polyhedron ◽  
2007 ◽  
Vol 26 (12) ◽  
pp. 2603-2611 ◽  
Author(s):  
Somnath Roy ◽  
Tarak Nath Mandal ◽  
Anil Kumar Barik ◽  
Sachindranath Pal ◽  
Samik Gupta ◽  
...  
2012 ◽  
Vol 65 (6) ◽  
pp. 1004-1016 ◽  
Author(s):  
Hassan Keypour ◽  
Maryam Shayesteh ◽  
Reza Golbedaghi ◽  
Abdolkarim Chehregani ◽  
Allan G. Blackman

2011 ◽  
Vol 365 (1) ◽  
pp. 25-31 ◽  
Author(s):  
Debdulal Maity ◽  
Shouvik Chattopadhyay ◽  
Ashutosh Ghosh ◽  
Michael G.B. Drew ◽  
Gurucharan Mukhopadhyay

2014 ◽  
Vol 1 (1) ◽  
pp. 1-14 ◽  
Author(s):  
Shingo Orita ◽  
Takashiro Akitsu

New mononuclear [Cu2(L1)2(H2O)]2H2O・CH3OH] (cyCu)2, multinuclear [Cu2(L1)2K2][Ni(CN)4] (cyCuKNi), and dinuclear Ni(L1)Lu(NO3)3 (cyLuNi), Cu(L1)Lu(NO3)3 (cyLuCu) and Zn(L1)Lu[(NO3)2CH3COO]CH3OH (cyLuZn) complexes incorporating chiral Schiff base ligands were prepared and characterized by various techniques such as solid-state CD spectra, diffuse reflectance electronic spectra, IR spectra, and single crystal X-ray diffraction analysis. Crystal structures were also compared with previous ones, namely [Cu(L2)](H2O) (diCu), Cu(L1)Gd(NO3)3 (cyGdCu). Interestingly, determined crystal structures exhibited drastically different structural characteristics as regards coordination numbers, crystalline solvents, features and strain condition, nevertheless with little modification in 3d metal substitution and/or modified organic ligands. In this paper, comparison of common components of structures will be discussed systematically.


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