Particle size and shell composition as effective parameters on MFFT for acrylic core–shell particles prepared via seeded emulsion polymerization

2014 ◽  
Vol 77 (11) ◽  
pp. 1874-1882 ◽  
Author(s):  
Iraj Hasanzadeh ◽  
Ali Reza Mahdavian ◽  
Hamid Salehi-Mobarakeh
Polymer ◽  
2016 ◽  
Vol 99 ◽  
pp. 324-331 ◽  
Author(s):  
Waraporn Wichaita ◽  
Duangporn Polpanich ◽  
Teeraporn Suteewong ◽  
Pramuan Tangboriboonrat

1986 ◽  
Vol 32 (5) ◽  
pp. 4865-4871 ◽  
Author(s):  
Yoshinobu Nakamura ◽  
Haruo Tabata ◽  
Hideto Suzuki ◽  
Kazuo Iko ◽  
Masayoshi Okubo ◽  
...  

2016 ◽  
Vol 473 ◽  
pp. 182-189 ◽  
Author(s):  
Liang Chen ◽  
Liang Hong ◽  
Jui-Ching Lin ◽  
Greg Meyers ◽  
Joseph Harris ◽  
...  

2012 ◽  
Vol 2012 ◽  
pp. 1-10 ◽  
Author(s):  
Diego Antonioli ◽  
Michele Laus ◽  
Giampaolo Zuccheri ◽  
Valerj Kapeliouchko ◽  
Maria Cristina Righetti ◽  
...  

The preparation of polytetrafluoroethylene-poly(methyl methacrylate) (PTFE-PMMA) core-shell particles was described, featuring controlled size and narrow size distribution over a wide compositional range, through a seeded emulsion polymerization starting from a PTFE seed of 26 nanometers. Over the entire MMA/PTFE range, the particle size increases as the MMA/PTFE ratio increases. A very precise control over the particle size can be exerted by properly adjusting the ratio between the monomer and the PTFE seed. Particles in the 80–240 nm range can be prepared with uniformity indexes suited to build 2D and 3D colloidal crystals. These core-shell particles were employed to prepare nanocomposites with different compositions, through an annealing procedure at a temperature higher than the glass transition temperature of the shell forming polymer. A perfect dispersion of the PTFE particles within the PMMA matrix was obtained and optically transparent nanocomposites were prepared containing a very high PTFE amount.


2014 ◽  
Vol 344 (1) ◽  
pp. 28-32
Author(s):  
Nilva R. Uliana ◽  
Ricardo A. F. Machado ◽  
Claudia Sayer ◽  
Pedro H.H. Araújo

RSC Advances ◽  
2016 ◽  
Vol 6 (42) ◽  
pp. 35621-35627 ◽  
Author(s):  
Ren He ◽  
Xiaoli Zhan ◽  
Qinghua Zhang ◽  
Fengqiu Chen

Reactive core–shell particles for epoxy toughening were synthesized via reversible addition–fragmentation chain transfer emulsion polymerization mediated by an amphiphilic macro-RAFT agent followed by core-crosslinking to increase stability.


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