Degradable Polymers via Olefin Metathesis Polymerization

Author(s):  
Hao Sun ◽  
Yifei Liang ◽  
Matthew P. Thompson ◽  
Nathan C. Gianneschi
2008 ◽  
Vol 130 (33) ◽  
pp. 11040-11048 ◽  
Author(s):  
Stefan Hilf ◽  
Robert H. Grubbs ◽  
Andreas F. M. Kilbinger

2013 ◽  
Vol 135 (45) ◽  
pp. 16817-16820 ◽  
Author(s):  
Raymond A. Weitekamp ◽  
Harry A. Atwater ◽  
Robert H. Grubbs

2019 ◽  
Vol 15 ◽  
pp. 310-332 ◽  
Author(s):  
Patrycja Żak ◽  
Cezary Pietraszuk

This mini-review summarizes the applications of olefin metathesis in synthesis and functionalization of polyhedral oligomeric silsesquioxanes (POSS) and POSS-containing polymeric materials. Three types of processes, i.e., cross metathesis (CM) of vinyl-substituted POSS with terminal olefins, acyclic diene metathesis (ADMET) copolymerization of divinyl-substituted POSS with α,ω-dienes and ring-opening metathesis polymerization (ROMP) of POSS-substituted norbornene (or other ROMP susceptible cycloolefins) are discussed. Emphasis was put on the synthetic and catalytic aspects rather than on the properties and applications of synthesized materials.


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