Synthetic strategies, properties, and applications of unsaturated main-chain metallopolymers prepared by olefin metathesis polymerization

2020 ◽  
pp. 1-41
Author(s):  
Ye Sha ◽  
Huan Jia ◽  
Zhihua Shen ◽  
Zhenyang Luo
Keyword(s):  
Olefin Metathesis ◽  
Main Chain ◽  
Metathesis Polymerization

End Capping Ring-Opening Olefin Metathesis Polymerization Polymers with Vinyl Lactones

2008 ◽  
Vol 130 (33) ◽  
pp. 11040-11048 ◽  
Author(s):  
Stefan Hilf ◽  
Robert H. Grubbs ◽  
Andreas F. M. Kilbinger
Keyword(s):  
Olefin Metathesis ◽  
Ring Opening ◽  
Metathesis Polymerization ◽  
End Capping

Photolithographic Olefin Metathesis Polymerization

2013 ◽  
Vol 135 (45) ◽  
pp. 16817-16820 ◽  
Author(s):  
Raymond A. Weitekamp ◽  
Harry A. Atwater ◽  
Robert H. Grubbs
Keyword(s):  
Olefin Metathesis ◽  
Metathesis Polymerization

scholarly journals Grubbs’ and Schrock’s Catalysts, Ring Opening Metathesis Polymerization and Molecular Brushes—Synthesis, Characterization, Properties and Applications

Polymers ◽  
2019 ◽  
Vol 11 (2) ◽  
pp. 298 ◽  
Author(s):  
Ioannis Choinopoulos
Keyword(s):  
Metal Complexes ◽  
Ring Opening ◽  
Main Chain ◽  
Ring Opening Metathesis Polymerization ◽  
Metathesis Polymerization ◽  
Molecular Brushes

In this review, molecular brushes and other macromolecular architectures bearing a bottlebrush segment where the main chain is synthesized by ring opening metathesis polymerization (ROMP) mediated by Mo or Ru metal complexes are considered. A brief review of metathesis and ROMP is presented in order to understand the problems and the solutions provided through the years. The synthetic strategies towards bottlebrush copolymers are demonstrated and each one discussed separately. The initiators/catalysts for the synthesis of the backbone with ROMP are discussed. Syntheses of molecular brushes are presented. The most interesting properties of the bottlebrushes are detailed. Finally, the applications studied by different groups are presented.

scholarly journals Application of olefin metathesis in the synthesis of functionalized polyhedral oligomeric silsesquioxanes (POSS) and POSS-containing polymeric materials

2019 ◽  
Vol 15 ◽  
pp. 310-332 ◽  
Author(s):  
Patrycja Żak ◽  
Cezary Pietraszuk
Keyword(s):  
Olefin Metathesis ◽  
Ring Opening ◽  
Polymeric Materials ◽  
Acyclic Diene Metathesis ◽  
Polyhedral Oligomeric Silsesquioxanes ◽  
Ring Opening Metathesis Polymerization ◽  
Metathesis Polymerization ◽  
Cross Metathesis ◽  
Terminal Olefins ◽  
Synthesized Materials

This mini-review summarizes the applications of olefin metathesis in synthesis and functionalization of polyhedral oligomeric silsesquioxanes (POSS) and POSS-containing polymeric materials. Three types of processes, i.e., cross metathesis (CM) of vinyl-substituted POSS with terminal olefins, acyclic diene metathesis (ADMET) copolymerization of divinyl-substituted POSS with α,ω-dienes and ring-opening metathesis polymerization (ROMP) of POSS-substituted norbornene (or other ROMP susceptible cycloolefins) are discussed. Emphasis was put on the synthetic and catalytic aspects rather than on the properties and applications of synthesized materials.

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