Rate constants in quantum mechanical systems: A rigorous and practical path-integral formulation for computer simulations

1998 ◽  
Vol 293 (3-4) ◽  
pp. 209-220 ◽  
Author(s):  
Nilmadhab Chakrabarti ◽  
Tucker Carrington Jr ◽  
Benoı̂t Roux
2020 ◽  
Vol 2020 (12) ◽  
Author(s):  
Naohisa Sueishi ◽  
Syo Kamata ◽  
Tatsuhiro Misumi ◽  
Mithat Ünsal

Abstract There are two well-known approaches to studying nonperturbative aspects of quantum mechanical systems: saddle point analysis of the partition functions in Euclidean path integral formulation and the exact-WKB analysis based on the wave functions in the Schrödinger equation. In this work, based on the quantization conditions obtained from the exact-WKB method, we determine the relations between the two formalism and in particular show how the two Stokes phenomena are connected to each other: the Stokes phenomenon leading to the ambiguous contribution of different sectors of the path integral formulation corresponds to the change of the “topology” of the Stoke curves in the exact-WKB analysis. We also clarify the equivalence of different quantization conditions including Bohr-Sommerfeld, path integral and Gutzwiller’s ones. In particular, by reorganizing the exact quantization condition, we improve Gutzwiller’s analysis in a crucial way by bion contributions (incorporating complex periodic paths) and turn it into an exact result. Furthermore, we argue the novel meaning of quasi-moduli integral and provide a relation between the Maslov index and the intersection number of Lefschetz thimbles.


2001 ◽  
Vol 115 (10) ◽  
pp. 4484-4495 ◽  
Author(s):  
Nicholas V. Blinov ◽  
Pierre-Nicholas Roy ◽  
Gregory A. Voth

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