Redox and isocyanide substitution chemistry of bis(2,2′-bipyridine) derivatives of molybdenum and tungsten carbonyl

1981 ◽  
Vol 218 (2) ◽  
pp. C31-C33 ◽  
Author(s):  
J.A. Connor ◽  
E.J. James ◽  
C. Overton ◽  
N. El Murr
Keyword(s):  
Tungsten Carbonyl ◽  
Substitution Chemistry ◽  
Derivatives Of ◽  
And Tungsten

Chromium, molybdenum and tungsten carbonyl derivatives of distibinomethane ligands †

1998 ◽  
pp. 825-832 ◽  
Author(s):  
Angela M. Hill ◽  
Nicholas J. Holmes ◽  
Anthony R. J. Genge ◽  
William Levason ◽  
Michael Webster ◽  
...  
Keyword(s):  
Carbonyl Derivatives ◽  
Tungsten Carbonyl ◽  
Derivatives Of ◽  
And Tungsten

Organometallic Derivatives of Orotic Acid. CO−Labilizing Ability of the Amido Group in Chromium and Tungsten Carbonyl Complexes

1998 ◽  
Vol 37 (10) ◽  
pp. 2538-2546 ◽  
Author(s):  
Donald J. Darensbourg ◽  
Jennifer D. Draper ◽  
David L. Larkins ◽  
Brian J. Frost ◽  
Joseph H. Reibenspies
Keyword(s):  
Orotic Acid ◽  
Carbonyl Complexes ◽  
Amido Group ◽  
Tungsten Carbonyl ◽  
Derivatives Of ◽  
And Tungsten

Carbonyl halides of the Group VI transition metals. XI. Dithiocyanatocarbonyl derivatives of molybdenum and tungsten(II)

1968 ◽  
Vol 21 (6) ◽  
pp. 1435 ◽  
Author(s):  
R Colton ◽  
GR Scollary
Keyword(s):  
Transition Metal ◽  
Transition Metals ◽  
Ammonium Chloride ◽  
Pure State ◽  
Ammonium Thiocyanate ◽  
Donor Ligands ◽  
Group Vi ◽  
Derivatives Of ◽  
And Tungsten

Reaction of ammonium thiocyanate with dihalocarbonyls of molybdenum and tungsten(11) leads to the elimination of ammonium chloride and the formation of a dithiocyanatocarbonyl complex of the transition metal. Although the thiocyanatocarbonyls themselves have not been isolated in a pure state, a number of substituted derivatives with phosphorus donor ligands have been prepared and characterized. In general these complexes are less stable than the corresponding carbonyl halide derivatives.

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