Carbon-rich organometallic materials derived from 4-ethynylphenylferrocene

2003 ◽  
Vol 683 (2) ◽  
pp. 341-353 ◽  
Author(s):  
Wai-Yeung Wong ◽  
Ka-Yan Ho ◽  
Sze-Ling Ho ◽  
Zhenyang Lin
Keyword(s):  
Organometallic Materials

scholarly journals Cover Picture: Assembly of Hybrid Organic–Organometallic Materials through Mechanochemical Acid–Base Reactions (Chem. Eur. J. 18/2003)

2003 ◽  
Vol 9 (18) ◽  
pp. 4273-4273
Author(s):  
Dario Braga ◽  
Lucia Maini ◽  
Marco Polito ◽  
Laurent Mirolo ◽  
Fabrizia Grepioni
Keyword(s):  
Acid Base ◽  
Organometallic Materials

New Synthesis/Processing Routes to Materials Exhibiting Large Optical Nonlinearity

1989 ◽  
Vol 175 ◽  
Author(s):  
L. R. Dalton ◽  
L. P. Yu
Keyword(s):  
Polymer Composites ◽  
Optical Nonlinearity ◽  
Optical Quality ◽  
Wave Mixing ◽  
Metal Phthalocyanine ◽  
Third Order ◽  
Polymer Backbone ◽  
New Synthesis ◽  
Polymer Solubility ◽  
Organometallic Materials

AbstractSynthesis/processing schemes for the preparation of optical quality thin films of π-electron containing organic and organometallic materials are discussed. Fabrication approaches range from preparation of molecular/polymer composites, to preparation of copolymers containing pendant electroactive moieties, to preparation of copolymers with electroactive units incorporated into the polymer backbone, to the preparation of polymer/polymer composites. Such fabrication methodologies (particularly the latter three approaches) have the advantage of facilitating control over polymer solubility and of avoiding aggregation of electroactive units. The synthetic schemes discussed here yield materials with well-defined electroactive units; thus, diffuse bandedges associated with a distribution of π-electron conjugation lengths are avoided. Degenerate four wave mixing (DFWM) measurements at 532, 579–600, and 1064 nm are used to determine third order susceptibilities. Investigation of the frequency dependence of χ(3)/α established that resonance contributions dominate non-linear optical activity near the π-iπ* bandedge. A variety of electroactive moieties have been investigated with the largest values of χ(3)/α (= 10−12 esu cm) being observed for triphenodioxazine, metal phthalocyanine, metal tetraazaannulene, 6,6′-dimethoxy-quinolidine cyanine units.

Hazardous Inorganic and Organometallic Materials

2017 ◽  
pp. 177-193
Author(s):  
Stanley E. Manahan
Keyword(s):  
Organometallic Materials

Exploring organo-palladium(II) complexes as novel organometallic materials for Li-ion batteries

2020 ◽  
Vol 337 ◽  
pp. 135659 ◽  
Author(s):  
Koffi Sénam Etsè ◽  
Frédéric Boschini ◽  
Claude Karegeya ◽  
Edith Roex ◽  
Guillermo Zaragoza ◽  
...  
Keyword(s):  
Li Ion Batteries ◽  
Li Ion ◽  
Organometallic Materials

New organometallic materials for nonlinear optics: metal σ-arylacetylides

1996 ◽  
Author(s):  
Stephan Houbrechts ◽  
Koen J. Clays ◽  
Andre P. Persoons ◽  
Victorio Cadierno ◽  
M. P. Gamasa ◽  
...  
Keyword(s):  
Nonlinear Optics ◽  
Organometallic Materials

Assembly of Hybrid Organic–Organometallic Materials through Mechanochemical Acid–Base Reactions

2003 ◽  
Vol 9 (18) ◽  
pp. 4362-4370 ◽  
Author(s):  
Dario Braga ◽  
Lucia Maini ◽  
Marco Polito ◽  
Laurent Mirolo ◽  
Fabrizia Grepioni
Keyword(s):  
Acid Base ◽  
Organometallic Materials
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