Inductive charge dispersal in the solvolysis of 3-substituted bicyclo[1.1.1] pentyl bromides

1991 ◽  
Vol 32 (42) ◽  
pp. 5945-5948 ◽  
Author(s):  
Cyril A. Grob ◽  
Cheng Xi Yang ◽  
Ernest W. Della ◽  
Dennis K. Taylor
Keyword(s):  

The object of the present series of researches is to examine how far the principal general facts in electricity are explicable on the theory adopted by the author, and detailed in his last memoir, re­lative to the nature of inductive action. The operation of a body charged with electricity, of either the positive or negative kind, on other bodies in its vicinity, as long as it retains the whole of its charge, may be regarded as simple induction , in contradistinction to the effects which follow the destruction of this statical equilibrium, and imply a transit of the electrical forces from the charged body to those at a distance, and which comprehend the phenomena of the electric discharge . Having considered, in the preceding paper, the process by which the former condition is established, and which consists in the successive polarization of series of contiguous particles of the interposed insulating dielectric; the author here proceeds to trace the process, which, taking place consequently on simple induction, terminates in that sudden, and often violent interchange of electric forces constituting disruption , or the electric discharge. He investigates, by the application of his theory, the gradual steps of transition which may be traced between perfect insulation on the one hand, and perfect conduction on the other, derived from the varied degrees of specific electric relations subsisting among the particular substances interposed in the circuit: and from this train of reasoning he deduces the conclusion that induction and conduction not only depend essentially on the same principles, but that they may be regarded as being of the same nature, and as differing merely in degree. The fact ascertained by Professor Wheatstone, that electric conduction, even in the most perfect conductors, as the metals, requires for its completion a certain appreciable time, is adduced in corrobo­ration of these views; for any retardation, however small, in the transmission of electric forces can result only from induction; the degree of retardation, and, of course, the time employed, being proportional to the capacity of the particles of the conducting body for retaining a given intensity of inductive charge. The more perfect insulators, as lac, glass and sulphur, are capable of retaining electri­city of high intensity; while, on the contrary, the metals and other excellent conductors, possess no power of retention when the in­tensity of the charge exceeds the lowest degrees. It would appear, however, that gases possess a power of perfect insulation, and that the effects generally referred to their capacity of conduction, are only the results of the carrying power of the charged particles either of the gas, or of minute particles of dust which may be present in them: and they perhaps owe their character of perfect insulators to their peculiar physical state, and to the condition of separation under which their particles are placed. The changes produced by heat on the conducting power of different bodies is not uniform; for in some, as sulphuret of silver and fluoride of lead, it is increased; while in others, as in the metals and the gases, it is diminished by an augmentation of temperature.


1985 ◽  
Vol 26 (26) ◽  
pp. 3083-3086 ◽  
Author(s):  
Francesco Fuso ◽  
Cyril A. Grob ◽  
Pawel Sawlewicz ◽  
Yao Guo-Wei
Keyword(s):  

1986 ◽  
Vol 17 (11) ◽  
Author(s):  
R. BIELMANN ◽  
C. A. GROB ◽  
D. KUERY ◽  
G. W. YAO
Keyword(s):  

2020 ◽  
Vol 64 (1-4) ◽  
pp. 1057-1064
Author(s):  
Dandan Liu ◽  
Mingming Jing ◽  
Dewen Li ◽  
Chongzhi Liu ◽  
Chunrui Tang

The accuracy of the existing dust measurement device comprising a straight pipe is not sufficiently high for low particle speeds. In this paper, a measuring pipe based on the Coanda effect is designed, an experimental model is established using Gambit 2.4, and a numerical simulation is performed using Fluent 6.3. In this way, speed nephograms at the middle section of the device pipe were obtained for different dust particle sizes. By comparing the velocity data of a devices comprising a straight tube, a venturi tube, or a Coanda tube, it was found that the velocity of the particles passing through the Coanda tube was higher than that for the other tubes. Therefore, the probability of frictional collision within the Coanda tube increases, thereby increasing the inductive charge of the particles. By calculating the electrostatic induction of the particles using MATLAB, it was found that the charge carried by the particles in the improved device significantly increased (25% on average). It is concluded that these findings are of significance for designing the structure of novel dust concentration measurement devices.


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