The role of the triplet state on the photobleaching processes of xanthene dyes in a poly(vinyl alcohol) matrix

2001 ◽  
Vol 139 (2-3) ◽  
pp. 187-197 ◽  
Author(s):  
M. Talhavini ◽  
W. Corradini ◽  
T.D.Z. Atvars
1981 ◽  
Vol 34 (7) ◽  
pp. 1367 ◽  
Author(s):  
R Sakurovs ◽  
KP Ghiggino

The temperature dependence of the fluorescence and phosphorescence from tyrosine and tryptophan in poly(vinyl alcohol) films has been studied over the temperature range 90-295 K. A kinetic scheme is proposed which allows the calculation of activation energies for excited singlet and triplet state deactivation processes. A single temperature-dependent radiationless process from the singlet state is observed for tyrosine and tryptophan, with activation energies of 5.2�0.4 and 7.1�0.6 kJ mol-1 respectively. However, two distinct temperature transitions have been detected for triplet-state relaxation at 180 and 255 K. The role of polymer phase transitions in determining excited state relaxation pathways of embedded luminescent probes is discussed.


1994 ◽  
Author(s):  
Rupak Changkakoti ◽  
Gurusamy Manivannan ◽  
Philippe E. Leclere ◽  
Roger A. Lessard ◽  
Danny Roberge ◽  
...  

Polymer ◽  
2010 ◽  
Vol 51 (3) ◽  
pp. 687-693 ◽  
Author(s):  
Kumiko Ohishi ◽  
Toshiaki Itadani ◽  
Tetsushi Hayashi ◽  
Toshio Nakai ◽  
Fumitaka Horii

Soft Matter ◽  
2018 ◽  
Vol 14 (32) ◽  
pp. 6767-6773 ◽  
Author(s):  
Jingjing Li ◽  
Zhijie Zhang ◽  
Xiao Cao ◽  
Yonggang Liu ◽  
Quan Chen

This study examined linear viscoelasticity of semidilute non-entangled poly(vinyl alcohol) (PVA) and borax aqueous solutions: one borax molecule dissociates into two B(OH)3 molecules and two B(OH)4− ions, and the latter can crosslink the PVA chains.


2008 ◽  
Vol 8 (3) ◽  
pp. 1060-1066 ◽  
Author(s):  
Anuj A. Vargeese ◽  
Satyawati. S. Joshi ◽  
V. N. Krishnamurthy

2014 ◽  
Vol 67 (1-2) ◽  
pp. 147-153 ◽  
Author(s):  
Jobin Jose ◽  
S. K De ◽  
Mariam Al-Ali AlMa'adeed ◽  
Jolly Bhadra Dakua ◽  
P. A Sreekumar ◽  
...  

RSC Advances ◽  
2020 ◽  
Vol 10 (65) ◽  
pp. 39531-39541
Author(s):  
Amina Allel ◽  
Mohamed Wahib Naceur ◽  
Hassiba Benguergoura ◽  
Alain Ledoux ◽  
Waseem Sharaf Saeed ◽  
...  

This work aims to study the role of bentonite, Na+ montmorillonite (Na+MMT), as a filler to design a new poly(vinyl alcohol) (PVA)-based membrane for the pervaporation of an azeotropic water/ethanol mixture to enhance its separation efficiency.


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