Rare-Earth Metal–Organic Framework@Graphene Oxide Composites As High-Efficiency Microwave Absorbents

Author(s):  
Yu Zhou ◽  
Liwei Zhu ◽  
Yanjian Wang ◽  
Liangmin Yu ◽  
Xia Li
Crystals ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 185
Author(s):  
Kai Song ◽  
Han Yu ◽  
Jingyi Zhang ◽  
Yumeng Bai ◽  
Yanjun Guan ◽  
...  

A rosebengal-modified nanoporous structure was designed and constructed. This composite structure consisted of an organic sensitizer based on rosebengal and a supporting host of rare earth metal-organic-framework (MOF). It was identified by means of its x-ray diffraction (XRD) pattern, Infrared (IR) spectra, thermal stability and photophysical measurements. Its absorption was increased by 2,4,6-trinitrophenol. Its rosebengal emission was proportionally increased. But its rare earth emission was well-preserved, offering ratiometric signals. These two sensing modes exhibited linear response and good selectivity with a limit of detection (LOD) of 1.9 μM. Its sensing nature was confirmed as the combination of increased rosebengal emission and rare earth emission quenching effect triggered electron-deficient molecules. This nanoporous structure was superior to traditional ones owing to its double sensing modes.


RSC Advances ◽  
2016 ◽  
Vol 6 (65) ◽  
pp. 60940-60944 ◽  
Author(s):  
Ming-Liang Gao ◽  
Na Wei ◽  
Zheng-Bo Han

An anionic metal–organic framework, (DMA)2[Y9(μ3-OH)8(μ2-OH)3BTB6]n·(solv)x, (gea-MOF-1), is a novel rare earth (RE) nonanuclear MOF with an unusual gea topology that can be used as an adsorbent material for efficient removal of cationic dye MB+.


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