Mechanochemical Synthesis, Characterization, and Structure Determination of New Alkaline Earth Metal-Tetrafluoroterephthalate Frameworks: Ca(pBDC-F4)·4H2O, Sr(pBDC-F4)·4H2O, and Ba(pBDC-F4)

2016 ◽  
Vol 16 (4) ◽  
pp. 1923-1933 ◽  
Author(s):  
Abdal-Azim Al-Terkawi ◽  
Gudrun Scholz ◽  
Franziska Emmerling ◽  
Erhard Kemnitz
Keyword(s):  
Mechanochemical Synthesis ◽  
Structure Determination ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal

scholarly journals Mechanochemistry of fluoride solids: from mechanical activation to mechanically stimulated synthesis

ChemTexts ◽  
2021 ◽  
Vol 7 (2) ◽  
Author(s):  
Gudrun Scholz
Keyword(s):  
Mechanical Activation ◽  
Mechanochemical Synthesis ◽  
Alkaline Earth ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Technical Equipment ◽  
Metal Compounds ◽  
Potential Applications ◽  
The Given ◽  
Mechanochemical Reactions

Abstract This lecture text is focused on the comparatively young field of mechanochemistry of fluoride solids, considering both their mechanical activation and their mechanochemical synthesis. Beside a literature survey, the mechanochemical synthesis of binary fluorides MF2, MF3, of complex fluorides MMgF4, of solid solutions MaxMb1−xF2 or M1−xLnxF2+x (Ln: Y, Eu) and of fluorine-containing coordination polymers is presented. Owing to their interesting potential applications in the field of fluoride ion conductivity or luminescence properties when doped, most of the given examples are alkaline earth metal compounds. A short historical survey, remarks on peculiarities and consequences of mechanical activation as well as the necessary technical equipment for mechanochemical reactions precede the section. Graphic abstract

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