Polymer–MOF Hybrid Composites with High Porosity and Stability through Surface-Selective Ligand Exchange

2018 ◽  
Vol 30 (23) ◽  
pp. 8639-8649 ◽  
Author(s):  
Vincent J. Pastore ◽  
Timothy R. Cook ◽  
Javid Rzayev
Author(s):  
Vera Truttmann ◽  
Stephan Pollitt ◽  
Hedda Drexler ◽  
Sreejith P. Nandan ◽  
Dominik Eder ◽  
...  

1995 ◽  
Vol 48 (5) ◽  
pp. 431-436 ◽  
Author(s):  
Sundaresan Vidyasankar ◽  
Pradeep K. Dhal ◽  
Sean D. Plunkett ◽  
Frances H. Arnold

2018 ◽  
Vol 9 ◽  
pp. 616-627 ◽  
Author(s):  
Yaroslav I Derikov ◽  
Georgiy A Shandryuk ◽  
Raisa V Talroze ◽  
Alexander A Ezhov ◽  
Yaroslav V Kudryavtsev

A fast route to transfer Au nanoparticles from aqueous to organic media is proposed based on the use of a high molecular mass diblock copolymer of styrene and 2-vinylpyridine for ligand exchange at the nanoparticle surface. The method enables the preparation of stable sols of Au nanorods with sizes of up to tens of nanometers or Au nanospheres in various organic solvents. By comparing the optical absorbance spectra of Au hydro- and organosols with the data of numerical simulations of the surface plasmon resonance, we find that nanoparticles do not aggregate and confirm the transmission electron microscopy data regarding their shape and size. The proposed approach can be effective in preparing hybrid composites without the use of strong thiol and amine surfactants.


Author(s):  
Jun Cong Ge ◽  
Sam Ki Yoon ◽  
Nag Jung Choi

Air pollutants such as volatile organic compounds (VOCs), nitrogen oxides (NOx), sulfur dioxide (SO2), as well as water pollutants including heavy metal, are harmful to human and environment. Effective control and reduction of their pollution is therefore an important topic for today’s scientists. Fly ash (FA) is a type of industrial waste that can cause multiple environmental problems if discharged into the air. On the other hand, because of its high porosity, large specific surface area, and other unique characteristics, the FA can also be used as a low-cost and high efficient adsorbent with some simple modifications. This paper reviews the effects of FA on treatment of the above air and water pollution based on our research experience over many years, including to the current status of global FA utilization, physicochemical properties, principle of adsorption, and the application direction of FA in the future. It focuses on the use of nanocomposite technology to fabricate functional FA fibrous membranes to adsorb VOCs from air, and treat heavy metal wastewater. This present review first describes the fabrication technology of FA nanocomposites and their mechanism of adsorption VOCs from air. Utilization of nanofiber technology to fabricate multi-functional FA emerging composite materials to mitigate air and water pollution has great potential in the future, especially use of pollutant material to control other pollutants.


2020 ◽  
Vol 26 (34) ◽  
pp. 7595-7601 ◽  
Author(s):  
Yoko Sakata ◽  
Masahiro Okada ◽  
Munehiro Tamiya ◽  
Shigehisa Akine

2015 ◽  
Vol 2015 (17) ◽  
pp. 2889-2894 ◽  
Author(s):  
Johannes Kreutzer ◽  
Matthias Czakler ◽  
Michael Puchberger ◽  
Ernst Pittenauer ◽  
Ulrich Schubert

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