Controllable Strategy for Metal–Organic Framework Light-Driven [2 + 2] Cycloaddition Reactions via Solvent-Assisted Linker Exchange

2021 ◽  
Author(s):  
Li-Hui Cao ◽  
Xiao-Qian Xu ◽  
Xiao-Han Tang ◽  
Yan Yang ◽  
Junyi Liu ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Cycloaddition Reactions ◽  
Metal Organic ◽  
Linker Exchange ◽  
Organic Framework

scholarly journals Vapor‐Phase Linker Exchange of the Metal–Organic Framework ZIF‐8: A Solvent‐Free Approach to Post‐synthetic Modification

2019 ◽  
Vol 58 (51) ◽  
pp. 18471-18475
Author(s):  
João Marreiros ◽  
Lenz Van Dommelen ◽  
Guillaume Fleury ◽  
Rodrigo Oliveira‐Silva ◽  
Timothée Stassin ◽  
...  
Keyword(s):  
Vapor Phase ◽  
Metal Organic Framework ◽  
Solvent Free ◽  
Metal Organic ◽  
Linker Exchange ◽  
Organic Framework

Combining Linker Design and Linker-Exchange Strategies for the Synthesis of a Stable Large-Pore Zr-Based Metal–Organic Framework

2018 ◽  
Vol 10 (41) ◽  
pp. 35462-35468 ◽  
Author(s):  
Hue T. T. Nguyen ◽  
Thach N. Tu ◽  
My V. Nguyen ◽  
Tien H. N. Lo ◽  
Hiroyasu Furukawa ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Large Pore ◽  
Metal Organic ◽  
Linker Exchange ◽  
Organic Framework

Functionalized Defects through Solvent-Assisted Linker Exchange: Synthesis, Characterization, and Partial Postsynthesis Elaboration of a Metal–Organic Framework Containing Free Carboxylic Acid Moieties

2015 ◽  
Vol 54 (4) ◽  
pp. 1785-1790 ◽  
Author(s):  
Olga Karagiaridi ◽  
Nicolaas A. Vermeulen ◽  
Rachel C. Klet ◽  
Timothy C. Wang ◽  
Peyman Z. Moghadam ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Linker Exchange ◽  
Organic Framework

scholarly journals Control over Catenation in Pillared Paddlewheel Metal–Organic Framework Materials via Solvent-Assisted Linker Exchange

2013 ◽  
Vol 25 (5) ◽  
pp. 739-744 ◽  
Author(s):  
Wojciech Bury ◽  
David Fairen-Jimenez ◽  
Marianne B. Lalonde ◽  
Randall Q. Snurr ◽  
Omar K. Farha ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Framework Materials ◽  
Metal Organic ◽  
Linker Exchange ◽  
Organic Framework

Molecular Encapsulation beyond the Aperture Size Limit through Dissociative Linker Exchange in Metal–Organic Framework Crystals

2014 ◽  
Vol 136 (36) ◽  
pp. 12540-12543 ◽  
Author(s):  
Joseph V. Morabito ◽  
Lien-Yang Chou ◽  
Zhehui Li ◽  
Cesar M. Manna ◽  
Christopher A. Petroff ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Aperture Size ◽  
Molecular Encapsulation ◽  
Size Limit ◽  
Metal Organic ◽  
Linker Exchange ◽  
Organic Framework

scholarly journals Vapor-Phase Linker Exchange of the Metal-Organic Framework ZIF-8: A Solvent-Free Approach to Post-Synthetic Modification

2019 ◽  
Author(s):  
Joao Marreiros ◽  
Lenz Van Dommelen ◽  
Guillaume Fleury ◽  
Rodrigo de Oliveira-Silva ◽  
Timothée Stassin ◽  
...  
Keyword(s):  
Single Crystal ◽  
Vapor Phase ◽  
Metal Organic Framework ◽  
Solvent Free ◽  
Metal Organic ◽  
Crystal Core ◽  
Linker Exchange ◽  
Selection Of ◽  
Organic Framework

Here we present a novel, solvent-free approach to post-synthetic linker exchange in ZIF-8 through exposure to linker vapor. As in the solvent-based approach, this vapor-phase linker exchange (VPLE) method retains the parent SOD topology and proceeds in a single-crystal to single-crystal manner. The scope of linkers that can be incorporated through VPLE was studied and criteria for the selection of further candidates were formulated. In large crystals, the incoming linker was found to form domains instead of distributing homogeneously, similar as for solution-based linker exchange. In contrast to the latter approach, VPLE yields a higher concentration of the incoming linker in the crystal core instead of the shell.

scholarly journals Vapor‐Phase Linker Exchange of the Metal–Organic Framework ZIF‐8: A Solvent‐Free Approach to Post‐synthetic Modification

2019 ◽  
Vol 131 (51) ◽  
pp. 18642-18646
Author(s):  
João Marreiros ◽  
Lenz Van Dommelen ◽  
Guillaume Fleury ◽  
Rodrigo Oliveira‐Silva ◽  
Timothée Stassin ◽  
...  
Keyword(s):  
Vapor Phase ◽  
Metal Organic Framework ◽  
Solvent Free ◽  
Metal Organic ◽  
Linker Exchange ◽  
Organic Framework

scholarly journals Strongly visible light-absorbing metal–organic frameworks functionalized by cyclometalated ruthenium(ii) complexes

RSC Advances ◽  
2020 ◽  
Vol 10 (15) ◽  
pp. 9052-9062
Author(s):  
Eirik Mydske Thoresen ◽  
Sigurd Øien-Ødegaard ◽  
Gurpreet Kaur ◽  
Mats Tilset ◽  
Karl Petter Lillerud ◽  
...  
Keyword(s):  
Visible Light ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Linker Exchange ◽  
Organic Framework

The metal–organic framework (MOF) UiO-67 was functionalized by incorporating different cyclometalated ruthenium(ii) complexes using three different methods: premade linker synthesis, postsynthetic functionalization, and postsynthetic linker exchange.

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