Prediction of Solution Behavior via Calorimetric Measurements Allows for Detailed Elucidation of Polyoxometalate Transformation

2021 ◽  
Author(s):  
Hrafn Traustason ◽  
Haylie L. Lobeck ◽  
Patrick A. Julien ◽  
Mengyu Xu ◽  
Mateusz Dembowski ◽  
...  
Keyword(s):  
Solution Behavior ◽  
Calorimetric Measurements

Water soluble palladium(ii) and platinum(ii) acyclic diaminocarbene complexes: solution behavior, DNA binding, and antiproliferative activity

2020 ◽  
Vol 44 (15) ◽  
pp. 5762-5773 ◽  
Author(s):  
Tatiyana V. Serebryanskaya ◽  
Mikhail A. Kinzhalov ◽  
Vladimir Bakulev ◽  
Georgii Alekseev ◽  
Anastasiya Andreeva ◽  
...  
Keyword(s):  
Dna Binding ◽  
Antiproliferative Activity ◽  
Water Soluble ◽  
Solution Behavior ◽  
Antitumor Potential ◽  
Acyclic Diaminocarbene

Water soluble Pd(ii) and Pt(ii)–ADC species synthesized via the metal-mediated coupling of isocyanides and 1,2-diaminobenzene have demonstrated antitumor potential.

Theoretical and Experimental Evaluation of the Effect of Fluorinated Substituent on the Topological Landscape and Thermodynamic Stability of Zeolitic Imidazolate Framework Polymorphs

2018 ◽  
Author(s):  
Mihails Arhangelskis ◽  
Athanassis Katsenis ◽  
Novendra Novendra ◽  
Zamirbek Akimbekov ◽  
Dayaker Gandrath ◽  
...  
Keyword(s):  
Density Functional Theory ◽  
Mechanochemical Synthesis ◽  
Thermodynamic Stability ◽  
Experimental Evaluation ◽  
Density Functional ◽  
Theoretical Calculations ◽  
Zeolitic Imidazolate Framework ◽  
Functional Theory ◽  
Calorimetric Measurements ◽  
And Calorimetry

By combining mechanochemical synthesis and calorimetry with theoretical calculations, we demonstrate that dispersion-corrected periodic density functional theory (DFT) can accurately survey the topological landscape and predict relative energies of polymorphs for a previously inaccessible fluorine-substituted zeolitic imidazolate framework (ZIF). Experimental screening confirmed two out of three theoretically anticipated polymorphs, and the calorimetric measurements provided an excellent match to theoretically calculated energetic difference between them.<br>

Solution behavior of quenched or strongly charged polyampholytes in aqueous-salt solutions

2019 ◽  
Vol 94 (2) ◽  
pp. 35-44 ◽  
Author(s):  
G. Toleutay ◽  
◽  
A.V. Shakhvorostov ◽  
S.K. Kabdrakhmanova ◽  
S.E. Kudaibergenov ◽  
...  
Keyword(s):  
Salt Solutions ◽  
Solution Behavior ◽  
Aqueous Salt Solutions

Solution Behavior of Poly(styrene)-block-poly(2-vinylpyridine) Micelles Containing Gold Nanoparticles

2000 ◽  
Vol 33 (13) ◽  
pp. 4791-4798 ◽  
Author(s):  
Stefan Mössmer ◽  
Joachim P. Spatz ◽  
Martin Möller ◽  
Thomas Aberle ◽  
Jürgen Schmidt ◽  
...  
Keyword(s):  
Gold Nanoparticles ◽  
Solution Behavior

Poly(styrene-graft-hyperbranched polyglycidol): synthesis and solution behavior of a hyperbranched polyelectrolyte

RSC Advances ◽  
2015 ◽  
Vol 5 (8) ◽  
pp. 5611-5616 ◽  
Author(s):  
Andrew Goodwin ◽  
Sachin Bobade ◽  
Nam-Goo Kang ◽  
Durairaj Baskaran ◽  
Kunlun Hong ◽  
...  
Keyword(s):  
Conformational Changes ◽  
Solution Behavior ◽  
Synthetic Procedure

This work presents a three-step synthetic procedure to obtain a hypergrafted copolymer composed of a glassy backbone with flexible branched pendant segments. The polymer exhibited polyelectrolyte behavior and conformational changes prior to neutralization with LiBr salt.

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