Construction of Stable Metal–Organic Framework Platforms Embedding N-Heterocyclic Carbene Metal Complexes for Selective Catalysis

2021 ◽  
Author(s):  
Hyunyong Kim ◽  
Hyunseok Kim ◽  
Kimoon Kim ◽  
Eunsung Lee
Keyword(s):  
Metal Complexes ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Selective Catalysis ◽  
Organic Framework

A dual-functional Cd(ii)–organic-framework demonstrating selective sensing of Zn2+ and Fe3+ ions exclusively and size-selective catalysis towards cyanosilylation

RSC Advances ◽  
2015 ◽  
Vol 5 (14) ◽  
pp. 10119-10124 ◽  
Author(s):  
Xiao-Nan Zhang ◽  
Lin Liu ◽  
Zheng-Bo Han ◽  
Ming-Liang Gao ◽  
Da-Qiang Yuan
Keyword(s):  
Metal Ions ◽  
Metal Organic Framework ◽  
Mixed Metal ◽  
Dual Functional ◽  
Metal Organic ◽  
Selective Catalysis ◽  
Organic Framework

A dual-functional metal–organic-framework can selectively sense Zn2+ and Fe3+ ions over mixed metal ions and displays size-selective catalysis towards cyanosilylation of aldehydes.

scholarly journals Functionalising metal–organic frameworks with metal complexes: the role of structural dynamics

CrystEngComm ◽  
2015 ◽  
Vol 17 (40) ◽  
pp. 7632-7635 ◽  
Author(s):  
Ana E. Platero-Prats ◽  
Antonio Bermejo Gómez ◽  
Karena W. Chapman ◽  
Belén Martín-Matute ◽  
Xiaodong Zou
Keyword(s):  
Metal Complexes ◽  
Structural Dynamics ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
The Impact ◽  
Organic Framework

The impact of dynamics in the functionalisation of metal–organic framework UiO-67 with an Ir-complex has been studied. Highly functionalised Ir-UiO-67 can be only trapped as kinetic products, which lose metals and exchange species to gain stability.

Review for chiral-at-metal complexes and metal-organic framework enantiomorphs

2017 ◽  
Vol 62 (19) ◽  
pp. 1344-1354 ◽  
Author(s):  
Zi-Hong Yan ◽  
Donghao Li ◽  
Xue-Bo Yin
Keyword(s):  
Metal Complexes ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework
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