Metal–Metal Bonding in Trinuclear, Mixed-Valence [Ti3X12]4– (X = F, Cl, Br, I) Face-Shared Complexes

2015 ◽  
Vol 54 (22) ◽  
pp. 10632-10641 ◽  
Author(s):  
Jinasena W. Hewage ◽  
Germán Cavigliasso ◽  
Robert Stranger
Keyword(s):  
Mixed Valence ◽  
Metal Bonding ◽  
Metal Metal

Metal−Metal Bonding in Mixed Valence Ni25+Complexes and Spectroscopic Evidence for a Ni26+Species

2006 ◽  
Vol 45 (11) ◽  
pp. 4396-4406 ◽  
Author(s):  
John F. Berry ◽  
Eberhard Bothe ◽  
F. Albert Cotton ◽  
Sergey A. Ibragimov ◽  
Carlos A. Murillo ◽  
...  
Keyword(s):  
Mixed Valence ◽  
Spectroscopic Evidence ◽  
Metal Bonding ◽  
Metal Metal

Ultrahard magnetism from mixed-valence dilanthanide complexes with metal-metal bonding

Science ◽  
2022 ◽  
Vol 375 (6577) ◽  
pp. 198-202
Author(s):  
Colin A. Gould ◽  
K. Randall McClain ◽  
Daniel Reta ◽  
Jon G. C. Kragskow ◽  
David A. Marchiori ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Liquid Nitrogen ◽  
Coordination Compounds ◽  
Mixed Valence ◽  
Liquid Nitrogen Temperature ◽  
Molecular Magnets ◽  
The Other ◽  
Metal Bonding ◽  
Metal Metal ◽  
Valence Electrons

Magnetic effects of lanthanide bonding Lanthanide coordination compounds have attracted attention for their persistent magnetic properties near liquid nitrogen temperature, well above alternative molecular magnets. Gould et al . report that introducing metal-metal bonding can enhance coercivity. Reduction of iodide-bridged terbium or dysprosium dimers resulted in a single electron bond between the metals, which enforced alignment of the other valence electrons. The resultant coercive fields exceeded 14 tesla below 50 and 60 kelvin for the terbium and dysprosium compounds, respectively. —JSY

Long-range metal-metal bonding in mixed-valence square planar complexes

1972 ◽  
Vol 8 (2) ◽  
pp. 173-179 ◽  
Author(s):  
Frank N. Lecrone ◽  
Michael J. Minot ◽  
Jerome H. Perlstein
Keyword(s):  
Long Range ◽  
Mixed Valence ◽  
Metal Bonding ◽  
Square Planar ◽  
Metal Metal ◽  
Square Planar Complexes

Metal-metal bonding and mixed-valent tantalum in La2Ta3S2O8

1992 ◽  
Vol 98 (1) ◽  
pp. 82-89 ◽  
Author(s):  
Theodore D. Brennan ◽  
James A. Ibers
Keyword(s):  
Metal Bonding ◽  
Metal Metal

MC4:  A Hypothetical Three-Dimensional Organometallic Net with Metal−Metal Bonding and Polyacetylene Substructures

1996 ◽  
Vol 118 (42) ◽  
pp. 10294-10302 ◽  
Author(s):  
Norman Goldberg ◽  
Huang Tang ◽  
Nancy Kroohs ◽  
Roald Hoffmann
Keyword(s):  
Three Dimensional ◽  
Metal Bonding ◽  
Metal Metal

Metal-Metal Bonding in Biology: EXAFS Evidence for a 2.5 .ANG. Copper-Copper Bond in the CuA Center of Cytochrome Oxidase

Biochemistry ◽  
1994 ◽  
Vol 33 (34) ◽  
pp. 10401-10407 ◽  
Author(s):  
Ninian J. Blackburn ◽  
Mary E. Barr ◽  
William H. Woodruff ◽  
John van der Ooost ◽  
Simon de Vries
Keyword(s):  
Cytochrome Oxidase ◽  
Metal Bonding ◽  
Metal Metal
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