Regioselective Nitration of N-Alkyl Anilines using tert-Butyl Nitrite under Mild Condition

2018 ◽  
Vol 84 (1) ◽  
pp. 104-119 ◽  
Author(s):  
Priyanka Chaudhary ◽  
Surabhi Gupta ◽  
Nalluchamy Muniyappan ◽  
Shahulhameed Sabiah ◽  
Jeyakumar Kandasamy
Keyword(s):  
Mild Condition ◽  
Tert Butyl ◽  
Regioselective Nitration

Metal-free regioselective nitration of quinoxalin-2(1H)-ones with tert-butyl nitrite

2021 ◽  
Author(s):  
Zhen Wang ◽  
Yi-Na Li ◽  
Xue-Lin Li ◽  
Jin-Bo Wu ◽  
Hong Jiang ◽  
...  
Keyword(s):  
Metal Free ◽  
Tert Butyl ◽  
Regioselective Nitration

A metal-free coupling of quinoxalin-2(1H)-ones with tert-butyl nitrite has been developed. Distinctly from the previous functionalization of quinoxalin-2(1H)-ones, this nitration reaction took place selectively at the C7 or C5 position...

Fe-N-C Artificial Enzyme: Activation of Oxygen for Dehydrogenation and Monoxygenation of Organic Substrates under Mild Condition and Cancer Therapeutic Application

2018 ◽  
Author(s):  
Fei He ◽  
Li Mi ◽  
Yanfei Shen ◽  
Toshiyuki Mori ◽  
Songqin Liu ◽  
...  
Keyword(s):  
Mild Condition ◽  
Enzyme Activation ◽  
Artificial Enzymes ◽  
Organic Substrates ◽  
Artificial Enzyme ◽  
Therapeutic Application ◽  
Highly Efficient ◽  
Activation Of Oxygen

Developing highly efficient artificial enzymes that directly employ O<sub>2</sub> as terminal oxidant has long been pursued but has rarely achieved yet. We report Fe-N-C has unusual enzyme-like activity in both dehydrogenation and monoxygenation of organic substrates with ~100% selectivity by direct using O<sub>2</sub>.

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