Rapid Structural Analysis of Minute Quantities of Organic Solids by Exhausting 1H Polarization in Solid-State NMR Spectroscopy Under Fast Magic Angle Spinning

2021 ◽  
pp. 12067-12074
Author(s):  
Zhiwei Yan ◽  
Rongchun Zhang
Keyword(s):  
Solid State ◽  
Nmr Spectroscopy ◽  
Structural Analysis ◽  
Solid State Nmr ◽  
Magic Angle Spinning ◽  
Magic Angle ◽  
Organic Solids ◽  
Solid State Nmr Spectroscopy ◽  
Angle Spinning ◽  
Fast Magic Angle Spinning

Band-Selective1H−13C Cross-Polarization in Fast Magic Angle Spinning Solid-State NMR Spectroscopy

2008 ◽  
Vol 130 (51) ◽  
pp. 17216-17217 ◽  
Author(s):  
Ségolène Laage ◽  
Alessandro Marchetti ◽  
Julien Sein ◽  
Roberta Pierattelli ◽  
Hans Juergen Sass ◽  
...  
Keyword(s):  
Solid State ◽  
Nmr Spectroscopy ◽  
Solid State Nmr ◽  
Magic Angle Spinning ◽  
Magic Angle ◽  
Cross Polarization ◽  
Solid State Nmr Spectroscopy ◽  
Angle Spinning ◽  
Fast Magic Angle Spinning

scholarly journals 1020 MHz single-channel proton fast magic angle spinning solid-state NMR spectroscopy

2015 ◽  
Vol 261 ◽  
pp. 1-5 ◽  
Author(s):  
Manoj Kumar Pandey ◽  
Rongchun Zhang ◽  
Kenjiro Hashi ◽  
Shinobu Ohki ◽  
Gen Nishijima ◽  
...  
Keyword(s):  
Solid State ◽  
Nmr Spectroscopy ◽  
Solid State Nmr ◽  
Single Channel ◽  
Magic Angle Spinning ◽  
Magic Angle ◽  
Solid State Nmr Spectroscopy ◽  
Angle Spinning ◽  
Fast Magic Angle Spinning

scholarly journals Rapid structural analysis of minute quantities of organic solids by exhausting 1H polarization in solid-state NMR spectroscopy at fast MAS

2021 ◽  
Author(s):  
Zhiwei Yan ◽  
Rongchun Zhang
Keyword(s):  
Solid State ◽  
Nmr Spectroscopy ◽  
Structural Analysis ◽  
Chemical Shift ◽  
Solid State Nmr ◽  
Magic Angle Spinning ◽  
Magic Angle ◽  
Organic Solids ◽  
Solid State Nmr Spectroscopy ◽  
Experimental Time

Solid-state nuclear magnetic resonance (NMR) is a powerful and indispensable tool for structural and dynamic studies of various challenging systems. Nevertheless, it often suffers from significant limitations due to the inherent low signal sensitivity when low- nuclei are involved. Herein, we report an efficient solid-state NMR approach for rapid and efficient structural analysis of minute amounts of organic solids. By encoding staggered chemical shift evolution in the indirect dimension and staggered acquisition in 1H dimension, a proton-detected homonuclear 1H/1H and heteronuclear 13C/1H chemical shift correlation (HETCOR) spectrum can be obtained simultaneously in a single experiment at fast magic-angle-spinning (MAS) conditions with barely increasing experimental time, compared to conventional proton-detected HETCOR experiment. We establish that abundant 1H polarization can be efficiently manipulated and fully utilized in proton-detected solid-state NMR spectroscopy for extraction of more critical structural information and thus reduction of total experimental time.

Sign in / Sign up

Export Citation Format

Share Document