Ratiometric Sensing of Polycyclic Aromatic Hydrocarbons Using Capturing Ligand Functionalized Mesoporous Au Nanoparticles as a Surface-Enhanced Raman Scattering Substrate

Langmuir ◽  
2020 ◽  
Vol 36 (38) ◽  
pp. 11366-11373
Author(s):  
Dongjie Zhang ◽  
Rui Hao ◽  
Lingling Zhang ◽  
Hongjun You ◽  
Jixiang Fang
2015 ◽  
Vol 17 (33) ◽  
pp. 21158-21163 ◽  
Author(s):  
Meng Jiang ◽  
Zhijiang Qian ◽  
Xufeng Zhou ◽  
Xing Xin ◽  
Jinghua Wu ◽  
...  

A facile and convenient strategy to detect polycyclic aromatic hydrocarbons is presented, using graphene–Ag nanoparticle hybrids as a surface-enhanced Raman scattering substrate.


2020 ◽  
Vol 98 (2) ◽  
pp. 24-31
Author(s):  
R.Kh. Dzhanabekova ◽  
◽  
M.S. Kim ◽  
N.Kh. Ibrayev ◽  

The present work reports on the possibility of polycyclic aromatic hydrocarbons (PAHs) detection by surface enhanced Raman scattering (SERS) on substrates coated with colloidal silver stabilized with cetyltrimethylammonium bromide (CTAB). It was shown that cetyltrimethylammonium bromide acts not only as a stabilizer of metal nanoparticles, but also as modifying agent that promotes the concentration of hydrophobic PAH molecules near the amplified electromagnetic field of plasmon silver nanoparticles. Anthracene and pyrene were used as model analytes. To determine the sensitivity of the prepared SERS active coating, ethanol solutions of the analyzed substances with concentrations in the range of 2·10-4 — 10-6 mol/L were used. The lowest concentrations of solutions for which anthracene and pyrene are found on the tested substrates were equal to 2.5·10-6 M and 5·10-5 M, respectively. These results indicate that substrates are more sensitive to anthracene than to pyrene. The work also shows that various PAH molecules can be detected by characteristic peaks in a complex mixture without preliminary separation of the components.


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