Lithium Salt-Induced In Situ Living Radical Polymerizations Enable Polymer Electrolytes for Lithium-Ion Batteries

2021 ◽  
Vol 54 (2) ◽  
pp. 874-887
Author(s):  
Liping Yu ◽  
Yong Zhang ◽  
Jirong Wang ◽  
Huihui Gan ◽  
Shaoqiao Li ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Polymer Electrolytes ◽  
Lithium Salt ◽  
Lithium Ion ◽  
Living Radical Polymerizations ◽  
Radical Polymerizations

scholarly journals Development of the PEO Based Solid Polymer Electrolytes for All-Solid State Lithium Ion Batteries

Polymers ◽  
2018 ◽  
Vol 10 (11) ◽  
pp. 1237 ◽  
Author(s):  
Yu Jiang ◽  
Xuemin Yan ◽  
Zhaofei Ma ◽  
Ping Mei ◽  
Wei Xiao ◽  
...  
Keyword(s):  
Solid State ◽  
Lithium Ion Batteries ◽  
Polymer Electrolytes ◽  
High Performance ◽  
Lithium Salt ◽  
Rapid Development ◽  
Lithium Ion ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
Potential Candidate

Solid polymer electrolytes (SPEs) have attracted considerable attention due to the rapid development of the need for more safety and powerful lithium ion batteries. The prime requirements of solid polymer electrolytes are high ion conductivity, low glass transition temperature, excellent solubility to the conductive lithium salt, and good interface stability against Li anode, which makes PEO and its derivatives potential candidate polymer matrixes. This review mainly encompasses on the synthetic development of PEO-based SPEs (PSPEs), and the potential application of the resulting PSPEs for high performance, all-solid-state lithium ion batteries.

Internal in situ gel polymer electrolytes for high-performance quasi-solid-state lithium ion batteries

2019 ◽  
Vol 23 (10) ◽  
pp. 2785-2792 ◽  
Author(s):  
Dingsheng Shao ◽  
Xianyou Wang ◽  
Xiaolong Li ◽  
Kaili Luo ◽  
Li Yang ◽  
...  
Keyword(s):  
Solid State ◽  
Lithium Ion Batteries ◽  
Polymer Electrolytes ◽  
High Performance ◽  
Lithium Ion ◽  
Gel Polymer Electrolytes ◽  
In Situ Gel

In situ formation of polymer electrolytes using a dicationic imidazolium cross-linker for high-performance lithium ion batteries

2021 ◽  
Author(s):  
Yu-Chao Tseng ◽  
Shih-Hsien Hsiang ◽  
Chih-Hao Tsao ◽  
Hsisheng Teng ◽  
Sheng-Shu Hou ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Polymer Electrolytes ◽  
High Performance ◽  
Lithium Ion ◽  
In Situ Formation ◽  
Cross Linker

A dicationic imidazolium cross-linker is designed and further adopted as an electrolyte for lithium ion batteries.

scholarly journals Facile Fabrication of Polymer Electrolytes via Lithium Salt-Accelerated Thiol-Michael Addition for Lithium-Ion Batteries

2020 ◽  
Vol 53 (17) ◽  
pp. 7450-7459
Author(s):  
Ke Jiang ◽  
Jirong Wang ◽  
Cai Zuo ◽  
Shaoqiao Li ◽  
Sibo Li ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Michael Addition ◽  
Polymer Electrolytes ◽  
Lithium Salt ◽  
Lithium Ion ◽  
Facile Fabrication

scholarly journals In Situ Preparation of Crosslinked Polymer Electrolytes for Lithium Ion Batteries: A Comparison of Monomer Systems

Polymers ◽  
2020 ◽  
Vol 12 (8) ◽  
pp. 1707
Author(s):  
Eike T. Röchow ◽  
Matthias Coeler ◽  
Doris Pospiech ◽  
Oliver Kobsch ◽  
Elizaveta Mechtaeva ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Solid State ◽  
Ionic Conductivity ◽  
Lithium Ion Batteries ◽  
Polymer Electrolytes ◽  
Polymer Networks ◽  
Lithium Ion ◽  
Solid Polymer Electrolytes ◽  
Free Standing

Solid polymer electrolytes for bipolar lithium ion batteries requiring electrochemical stability of 4.5 V vs. Li/Li+ are presented. Thus, imidazolium-containing poly(ionic liquid) (PIL) networks were prepared by crosslinking UV-photopolymerization in an in situ approach (i.e., to allow preparation directly on the electrodes used). The crosslinks in the network improve the mechanical stability of the samples, as indicated by the free-standing nature of the materials and temperature-dependent rheology measurements. The averaged mesh size calculated from rheologoical measurements varied between 1.66 nm with 10 mol% crosslinker and 4.35 nm without crosslinker. The chemical structure of the ionic liquid (IL) monomers in the network was varied to achieve the highest possible ionic conductivity. The systematic variation in three series with a number of new IL monomers offers a direct comparison of samples obtained under comparable conditions. The ionic conductivity of generation II and III PIL networks was improved by three orders of magnitude, to the range of 7.1 × 10−6 S·cm−1 at 20 °C and 2.3 × 10−4 S·cm−1 at 80 °C, compared to known poly(vinylimidazolium·TFSI) materials (generation I). The transition from linear homopolymers to networks reduces the ionic conductivity by about one order of magnitude, but allows free-standing films instead of sticky materials. The PIL networks have a much higher voltage stability than PEO with the same amount and type of conducting salt, lithium bis(trifluoromethane sulfonyl)imide (LiTFSI). GII-PIL networks are electrochemically stable up to a potential of 4.7 V vs. Li/Li+, which is crucial for a potential application as a solid electrolyte. Cycling (cyclovoltammetry and lithium plating-stripping) experiments revealed that it is possible to conduct lithium ions through the GII-polymer networks at low currents. We concluded that the synthesized PIL networks represent suitable candidates for solid-state electrolytes in lithium ion batteries or solid-state batteries.

In-situ Synthesis of Solid-State Polymer Electrolytes for Lithium-Ion Batteries

2022 ◽  
pp. 193-209
Author(s):  
Yu-Chao Tseng ◽  
Ting-Yuan Lee ◽  
Yuan-Shuo Hsu ◽  
Febriana Intan ◽  
Jeng-Shiung Jan
Keyword(s):  
Solid State ◽  
Lithium Ion Batteries ◽  
Polymer Electrolytes ◽  
Lithium Ion ◽  
In Situ Synthesis
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