Polyethylene-g-poly(cyclohexene oxide) by Mechanistic Transformation from ROMP to Visible Light-Induced Free Radical Promoted Cationic Polymerization

2015 ◽  
Vol 48 (6) ◽  
pp. 1658-1663 ◽  
Author(s):  
Mustafa Ciftci ◽  
Senem Kork ◽  
Guangjuan Xu ◽  
Michael R. Buchmeiser ◽  
Yusuf Yagci
Keyword(s):  
Free Radical ◽  
Visible Light ◽  
Cationic Polymerization ◽  
Cyclohexene Oxide

A Visible Light Initiating System for Free Radical Promoted Cationic Polymerization

1994 ◽  
Vol 27 (14) ◽  
pp. 3683-3693 ◽  
Author(s):  
Yubai Bi ◽  
Douglas C. Neckers
Keyword(s):  
Free Radical ◽  
Visible Light ◽  
Cationic Polymerization

scholarly journals Self-strengthening hybrid dental adhesive via visible-light irradiation triple polymerization

RSC Advances ◽  
2016 ◽  
Vol 6 (57) ◽  
pp. 52434-52447 ◽  
Author(s):  
Linyong Song ◽  
Qiang Ye ◽  
Xueping Ge ◽  
Anil Misra ◽  
Candan Tamerler ◽  
...  
Keyword(s):  
Free Radical ◽  
Visible Light ◽  
Radical Polymerization ◽  
Visible Light Irradiation ◽  
Cationic Polymerization ◽  
Sol Gel ◽  
Free Radical Polymerization ◽  
Light Irradiation ◽  
Dental Adhesive ◽  
Polymerization System

An integrated triple polymerization system containing free radical polymerization, cationic polymerization, and photoacid-induced sol–gel reaction was designed and successfully applied to develop dental adhesive capable of self-strengthening property in wet environments.

Visible light-induced free radical promoted cationic polymerization using organotellurium compounds

2018 ◽  
Vol 9 (48) ◽  
pp. 5639-5643 ◽  
Author(s):  
Kerem Kaya ◽  
Mustafa Seba ◽  
Takehiro Fujita ◽  
Shigeru Yamago ◽  
Yusuf Yagci
Keyword(s):  
Free Radical ◽  
Visible Light ◽  
Cationic Polymerization ◽  
Cyclic Ethers ◽  
Organotellurium Compounds

In the present study, visible light and sunlight-induced cationic polymerization of vinyl and cyclic ethers using organotellurium compounds is demonstrated.

scholarly journals Photoinitiated cationic polymerization using allylsulfonium salts. Substituent effect on the initiator activity

e-Polymers ◽  
2001 ◽  
Vol 1 (1) ◽  
Author(s):  
Fatma Bayramoglu ◽  
Aysen Onen ◽  
Yusuf Yagci
Keyword(s):  
Electron Transfer ◽  
Free Radical ◽  
Cationic Polymerization ◽  
Substituent Effect ◽  
Cyclohexene Oxide ◽  
Cationic Photopolymerization ◽  
Transfer Mechanisms

AbstractAllylthiophenium salts with various substituents at the allylic moiety were synthesized, characterized and shown to be efficient coinitiators in radicallly promoted cationic photopolymerization of cyclohexene oxide. The relative efficiencies of these salts in combination with benzoin and benzophenone as free radical sources in the photopolymerizations are compared. Both additionfragmentation and electron transfer mechanisms are proposed and their relative merits discussed.

scholarly journals Carbazole-based compounds as photoinitiators for free radical and cationic polymerization upon near visible light illumination

2018 ◽  
Vol 17 (5) ◽  
pp. 578-585 ◽  
Author(s):  
Assi Al Mousawi ◽  
Ahmad Arar ◽  
Malika Ibrahim-Ouali ◽  
Sylvain Duval ◽  
Frédéric Dumur ◽  
...  
Keyword(s):  
Free Radical ◽  
Visible Light ◽  
Radical Polymerization ◽  
Cationic Polymerization ◽  
High Performance ◽  
Free Radical Polymerization ◽  
Light Illumination ◽  
Visible Light Illumination

Six new carbazole based compounds are synthesized and proposed as high performance photoinitiators for both the free radical polymerization of acrylates and the cationic polymerization of epoxides.

Visible light induced free radical promoted cationic polymerization using acylsilanes

2019 ◽  
Vol 132 ◽  
pp. 139-143 ◽  
Author(s):  
Erdem Sari ◽  
Moritz Mitterbauer ◽  
Robert Liska ◽  
Yusuf Yagci
Keyword(s):  
Free Radical ◽  
Visible Light ◽  
Cationic Polymerization
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