Influence of the 1,3-Bis(trimethylsilyl)cyclopentadienyl Ligand on the Reactivity of the Uranium Phosphinidene [η5-1,3-(Me3Si)2C5H3]2U(═P-2,4,6-iPr3C6H2)(OPPh3)

The title compound, [Co(C10H15)(C2H4)2], was prepared by Na/Hg reduction of [Co2(C10H15)2(μ-Cl)2] in THF under an ethylene atmosphere and crystallized from pentane at 193 K. The Co—C(olefin) bonds have an average length of 2.022 (2) Å, while the Co—C(pentadienyl) bonds average 2.103 (19) Å. The olefin C=C bonds are 1.410 (1) Å. The dihedral angle between the planes defined by the cyclopentadienyl ligand and the two olefin ligands is 0.25 (12)°. In the crystal, molecules are linked into chains by C—H...π interactions.

Download Full-text

Influence of the 1,3-Bis(trimethylsilyl)cyclopentadienyl Ligand on the Reactivity of the Uranium Phosphinidene [η5-1,3-(Me3Si)2C5H3]2U(═P-2,4,6-iPr3C6H2)(OPPh3)

A designed, enantiomerically pure, fused cyclopentadienyl ligand with C2 symmetry. Synthesis and use in enantioselective titanocene-catalyzed hydrogenations of alkenes

Acetyl substitution of the cyclopentadienyl ligand in molybdenum complexes; nucleophilic additions to coordinated allyl groups

Transition-Metal Complexes of the Optically Active Cyclopentadienyl Ligand PinCp*: Crystal Structure of (SRe)-(η5-PinCp*)Re(NO)(PPh3)[CONHCH(CH3)C10H7]

Chemistry of .eta.2-CS2 metal complexes. Comparison of the reactivities of the two isomeric heterometallacycles [cyclic] MoC(S)SC(R):CR and [cyclic] MoSC(S)C(R):CR. Unexpected formation of a carbon-carbon bond between the five-membered metalla ring and an .eta.5-cyclopentadienyl ligand

Exploring the Concept of Aromaticity on Complexes of a Fourfold Benzannulated Cyclopentadienyl Ligand

Addition and cycloaddition reactions of [Cp(CO)2Re.tplbond.CTol]+ with cis-azoarenes, epoxides, 3,3-dimethyloxetane, 2-methylaziridine, propylene sulfide, and benzophenone hydrazone. Displacement of the cyclopentadienyl ligand from the resultant metallacycles by trimethylphosphine

Pronounced Enhancement Brought in by Substituents on the Cyclopentadienyl Ligand: Catalyst System (C5Me4R)2Sm(THF)x/MMAO (R = Et,iPr,nBu, TMS; MMAO = Modified Methylaluminoxane) for 1,4-Cis Stereospecific Polymerization of 1,3-Butadiene in Cyclohexane Solvent

Syntheses and characterization of iridium and rhodium ethylene complexes containing a doubly linked cyclopentadienyl ligand

A novel chiral cyclopentadienyl ligand based on ephedrine

Crystal structure of bis(η2-ethylene)(η5-pentamethylcyclopentadienyl)cobalt

Transition-Metal Complexes of the Optically Active Cyclopentadienyl Ligand PinCp: Crystal Structure of (SRe)-(η5-PinCp)Re(NO)(PPh3)[CONHCH(CH3)C10H7]