Cooperative Bond Activation Reactions with Nickel and Palladium Carbene Complexes with a PCcarbeneS Pincer Ligand

Lithium- and magnesium complexes of a CNC pincer ligand composed of carbazole and two mesoionic carbenes are bright luminescent, because the metals prevent molecular distortions upon excitation.

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Orthometallation in iridium N-heterocycle stabilized carbene complexes via carbon halogen and carbon hydrogen bond activation induced by silver nanoparticles

Inorganica Chimica Acta ◽

10.1016/j.ica.2018.10.016 ◽

2019 ◽

Vol 486 ◽

pp. 1-7 ◽

Cited By ~ 2

Author(s):

Andrew C. Marr ◽

Graham C. Saunders ◽

Hayden P. Thomas ◽

Yue-Ming Wang

Keyword(s):

Hydrogen Bond ◽

Silver Nanoparticles ◽

Bond Activation ◽

Carbene Complexes ◽

Carbon Hydrogen Bond Activation

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C–H Bond Activation of Methane by PtII–N-Heterocyclic Carbene Complexes. The Importance of Having the Ligands in the Right Place at the Right Time

Organometallics ◽

10.1021/om201114d ◽

2012 ◽

Vol 31 (3) ◽

pp. 1042-1048 ◽

Cited By ~ 18

Author(s):

Bruce M. Prince ◽

Thomas R. Cundari

Keyword(s):

Bond Activation ◽

Carbene Complexes ◽

The Right

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Catalytic Carbon-Fluorine Bond Activation with Monocoordinated Nickel-Carbene Complexes: Reduction of Fluoroarenes

Advanced Synthesis & Catalysis ◽

10.1002/adsc.200390036 ◽

2003 ◽

Vol 345 (3) ◽

pp. 341-344 ◽

Cited By ~ 75

Author(s):

Sébastien Kuhl ◽

Raphaël Schneider ◽

Yves Fort

Keyword(s):

Bond Activation ◽

Carbene Complexes

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Modulating reactivity in iridium bis(N-heterocyclic carbene) complexes: influence of ring size on E–H bond activation chemistry

Dalton Transactions ◽

10.1039/c4dt01398k ◽

2014 ◽

Vol 43 (32) ◽

pp. 12288-12298 ◽

Cited By ~ 17

Author(s):

Nicholas Phillips ◽

Christina Y. Tang ◽

Rémi Tirfoin ◽

Michael J. Kelly ◽

Amber L. Thompson ◽

...

Keyword(s):

Bond Activation ◽

Ring Size ◽

Carbene Complexes

Critical influence of NHC ring size: highly labile [Ir(5-Mes)2(H)2]+can only be studied by trapping experiments, while [Ir(6-Mes)2(H)2]+and [Ir(6-Xyl)2(H)2]+are air/moisture stable.

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Silver(i) NHC mediated C–C bond activation of alkyl nitriles and catalytic efficiency in oxazoline synthesis

Chemical Communications ◽

10.1039/c5cc02558c ◽

2015 ◽

Vol 51 (41) ◽

pp. 8699-8701 ◽

Cited By ~ 21

Author(s):

Rachael Heath ◽

Helge Müller-Bunz ◽

Martin Albrecht

Keyword(s):

High Efficiency ◽

Bond Activation ◽

Aldol Condensation ◽

Bond Cleavage ◽

Catalytic Efficiency ◽

Carbene Complexes ◽

Ambient Temperatures ◽

Mild Conditions ◽

New Applications

C–C bond cleavage is achieved with silver carbene species under relatively mild conditions (80 °C) stoichiometrically, and aldol condensation is catalyzed at ambient temperatures in high efficiency, with turnover numbers up to 5000 h−1, thus disclosing new applications and synthetic opportunities based on easily accessible silver carbene complexes.

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