Radical Clock Probes to Determine Carbohydrate Radical Stabilities

Organic Letters ◽

10.1021/acs.orglett.0c00111 ◽

2020 ◽

Vol 22 (4) ◽

pp. 1525-1529

Author(s):

Yasemin Mai-Linde ◽

Torsten Linker

Keyword(s):

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Hydroxymethylcyclopropane on Oxygen-Covered Mo(110): A Radical Clock on a Surface

Journal of the American Chemical Society ◽

10.1021/ja002769h ◽

2000 ◽

Vol 122 (49) ◽

pp. 12395-12396 ◽

Author(s):

Ilona Kretzschmar ◽

Joshua A. Levinson ◽

Cynthia M. Friend

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Mechanistic studies of intramolecular CH insertion reaction of arylnitrenes: isotope effect, configurational purity and radical clock studies

Journal of Physical Organic Chemistry ◽

10.1002/poc.837 ◽

2004 ◽

Vol 18 (1) ◽

pp. 9-20 ◽

Author(s):

Shigeru Murata ◽

Yasuhiro Tsubone ◽

Reina Kawai ◽

Daisuke Eguchi ◽

Hideo Tomioka

Keyword(s):

Isotope Effect ◽

Insertion Reaction ◽

Mechanistic Studies ◽

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Promotion of Sandmeyer hydroxylation (homolytic hydroxydediazoniation) and hydrodediazoniation by chelation of the copper catalyst: bidentate ligandsSandmeyer reactions. Part 8. For part 7 see ref. 1.Electronic supplementary information (ESI) available: EPR evidence for the formation of binuclear complexes by 2-hydroxycarboxylates; reprise of the radical clock results for 2-hydroxycarboxylates. See http://www.rsc.org/suppdata/ob/b4/b404699d/

Organic & Biomolecular Chemistry ◽

10.1039/b404699d ◽

2004 ◽

Vol 2 (13) ◽

pp. 1838 ◽

Author(s):

Peter Hanson ◽

Simon C. Rowell ◽

Paul H. Walton ◽

Allan W. Timms

Keyword(s):

Copper Catalyst ◽

Supplementary Information ◽

Binuclear Complexes ◽

Electronic Supplementary Information ◽

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Radical-clock α-halo-esters as mechanistic probes for bisphosphine iron-catalyzed cross-coupling reactions

Tetrahedron ◽

10.1016/j.tet.2018.11.043 ◽

2019 ◽

Vol 75 (2) ◽

pp. 129-136 ◽

Author(s):

Lei Liu ◽

Wes Lee ◽

Jun Zhou ◽

Surjo Bandyopadhyay ◽

Osvaldo Gutierrez

Keyword(s):

Cross Coupling ◽

Coupling Reactions ◽

Cross Coupling Reactions ◽

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ChemInform Abstract: A Highly Efficient Radical Clock as a Probe of the Mechanism of Sulfone Halogenation by Perhaloalkanes.

Chemischer Informationsdienst ◽

10.1002/chin.198609109 ◽

1986 ◽

Vol 17 (9) ◽

Author(s):

B. VACHER ◽

A. SAMAT ◽

M. CHANON

Keyword(s):

Highly Efficient ◽

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A Radical Clock for Reactions of Epoxy Derivatives Induced by Titanocene Chloride

Synlett ◽

10.1055/s-0028-1087410 ◽

2008 ◽

Vol 2008 (20) ◽

pp. 3208-3212 ◽

Author(s):

A. Fernández-Mateos ◽

P. Teijón ◽

R. Clemente ◽

R. González

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Ring-opening radical clock reactions: many density functionals have difficulty keeping time

Organic & Biomolecular Chemistry ◽

10.1039/c0ob01246g ◽

2011 ◽

Vol 9 (9) ◽

pp. 3158 ◽

Author(s):

Iain D. Mackie ◽

Gino A. DiLabio

Keyword(s):

Ring Opening ◽

Density Functionals ◽

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ChemInform Abstract: The Cyclopropylmethyl Free Radical Clock. Calibration for the Range 30-89 °C.

10.1002/chin.198717113 ◽

1987 ◽

Vol 18 (17) ◽

Author(s):

L. MATHEW ◽

J. WARKENTIN

Keyword(s):

Free Radical ◽

Radical Clock ◽

Clock Calibration

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ChemInform Abstract: Kinetics for the Reaction of a Secondary Alkyl Radical with Tri-n-butylgermanium Hydride and Calibration of a Secondary Alkyl Radical Clock Reaction.

10.1002/chin.198802056 ◽

1988 ◽

Vol 19 (2) ◽

Author(s):

J. LUSZTYK ◽

B. MAILLARD ◽

S. DEYCARD ◽

D. A. LINDSAY ◽

K. U. INGOLD

Keyword(s):

Alkyl Radical ◽

Radical Clock ◽

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Oxidative N-Dealkylation ofp-Cyclopropyl-N,N-dimethylaniline. A Substituent Effect on a Radical-Clock Reaction Rationalized by Ab Initio Calculations on Radical Cation Intermediates

The Journal of Organic Chemistry ◽

10.1021/jo9709209 ◽

1997 ◽

Vol 62 (23) ◽

pp. 8227-8230 ◽

Author(s):

Hao Chen ◽

Marcel J. de Groot ◽

Nico P. E. Vermeulen ◽

Robert P. Hanzlik

Keyword(s):

Ab Initio Calculations ◽

Ab Initio ◽

Radical Cation ◽

Substituent Effect ◽

Radical Clock ◽

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