scholarly journals Correction to “Kinetic Resolution of 2H-Azirines by Asymmetric Allylation Reactions”

ACS Catalysis ◽  
2021 ◽  
pp. 14336-14337
Author(s):  
Yu-Liang Pan ◽  
Ying-Bo Shao ◽  
Jie Wang ◽  
Zhen Liu ◽  
Li Chen ◽  
...  
Keyword(s):  
Kinetic Resolution ◽  
Asymmetric Allylation

Kinetic Resolution via Palladium-Catalyzed Asymmetric Allylation

Synfacts ◽  
2012 ◽  
Vol 8 (03) ◽  
pp. 0282-0282
Keyword(s):  
Kinetic Resolution ◽  
Asymmetric Allylation ◽  
Palladium Catalyzed

Asymmetric synthesis of quaternary α-trifluoromethyl α-amino acids by Ir-catalyzed allylation followed by kinetic resolution

2020 ◽  
Vol 56 (22) ◽  
pp. 3333-3336 ◽  
Author(s):  
Xi-Shang Sun ◽  
Qiu Ou-Yang ◽  
Shi-Ming Xu ◽  
Xing-Heng Wang ◽  
Hai-Yan Tao ◽  
...  
Keyword(s):  
Amino Acids ◽  
Asymmetric Synthesis ◽  
Kinetic Resolution ◽  
Asymmetric Allylation ◽  
Sequential Reaction

Facile access to quaternary α-trifluoromethyl α-amino acids has been developed. This sequential reaction involves an Ir-catalyzed asymmetric allylation of α-trifluoromethyl aldimine esters followed by an unprecedented kinetic resolution.

scholarly journals Access to P-chiral sec- and tert-phosphine oxides enabled by Le-Phos-catalyzed asymmetric kinetic resolution

2020 ◽  
Vol 11 (36) ◽  
pp. 9983-9988
Author(s):  
Haile Qiu ◽  
Qiang Dai ◽  
Jiafeng He ◽  
Wenbo Li ◽  
Junliang Zhang
Keyword(s):  
Kinetic Resolution ◽  
Secondary Phosphine ◽  
Phosphine Oxides ◽  
Asymmetric Allylation

Herein we report an efficient kinetic resolution of secondary phosphine oxides via a Le-Phos-catalyzed asymmetric allylation reaction with Morita–Baylis–Hillman carbonates.

First Stereoselective Total Synthesis of Anti-Inflammatory Metabolite­ Penicillinolide A

Synthesis ◽  
2018 ◽  
Vol 51 (06) ◽  
pp. 1427-1434 ◽  
Author(s):  
Palakodety Krishna ◽  
Mopuri Reddy ◽  
Gembali Manikanta
Keyword(s):  
Total Synthesis ◽  
Kinetic Resolution ◽  
Asymmetric Allylation ◽  
Asymmetric Total Synthesis ◽  
Hydrolytic Kinetic Resolution ◽  
Anti Inflammatory ◽  
Key Steps

The first asymmetric total synthesis of penicillinolide A is described. Key steps of the synthesis involve Jacobsen’s hydrolytic kinetic resolution (HKR), chelation controlled allylation, Brown’s asymmetric allylation, hydroboration, and Yamaguchi lactonization.

ChemInform Abstract: A Highly Efficient Kinetic Resolution of Morita-Baylis-Hillman Adducts Achieved by N-Ar Axially Chiral Pd-Complexes Catalyzed Asymmetric Allylation.

ChemInform ◽  
2012 ◽  
Vol 43 (17) ◽  
pp. no-no
Author(s):  
Feijun Wang ◽  
Shengke Li ◽  
Mingliang Qu ◽  
Mei-Xin Zhao ◽  
Lian-Jun Liu ◽  
...  
Keyword(s):  
Kinetic Resolution ◽  
Asymmetric Allylation ◽  
Highly Efficient ◽  
Axially Chiral ◽  
Pd Complexes

First Stereoselective Total Synthesis of (3S,7R)-De-O-methylbotryosphaeriodiplodin

2019 ◽  
Vol 14 (1) ◽  
pp. 1934578X1901400
Author(s):  
Jhillu S. Yadav ◽  
Chitteti Divya Vani ◽  
Mule Chowdeswari ◽  
K. Ananthalakshmi ◽  
N. Bhasker ◽  
...  
Keyword(s):  
Total Synthesis ◽  
Macrocyclic Lactone ◽  
Kinetic Resolution ◽  
Asymmetric Allylation ◽  
Stille Coupling ◽  
Ring Closing Metathesis ◽  
Highly Efficient ◽  
Key Steps

A simple and highly efficient first stereoselective total synthesis of a benzofused macrocyclic lactone, ( 3S,7R)-de- O-methylbotryosphaeriodiplodin has been accomplished utilizing Jacobson's kinetic resolution, Marouka asymmetric allylation, Stille coupling, and ring-closing metathesis (RCM) reactions as key steps.

A highly efficient kinetic resolution of Morita–Baylis–Hillman adducts achieved by N–Ar axially chiral Pd-complexes catalyzed asymmetric allylation

2011 ◽  
Vol 47 (48) ◽  
pp. 12813 ◽  
Author(s):  
Feijun Wang ◽  
Shengke Li ◽  
Mingliang Qu ◽  
Mei-Xin Zhao ◽  
Lian-Jun Liu ◽  
...  
Keyword(s):  
Kinetic Resolution ◽  
Asymmetric Allylation ◽  
Highly Efficient ◽  
Axially Chiral ◽  
Pd Complexes

Synthesis of B-ring-fluorinated (−)-epicatechin gallate derivatives

2020 ◽  
Vol 18 (21) ◽  
pp. 4024-4028
Author(s):  
David D. S. Thieltges ◽  
Kai D. Baumgarten ◽  
Carina S. Michaelis ◽  
Constantin Czekelius
Keyword(s):  
Kinetic Resolution ◽  
Convergent Sequence ◽  
Epicatechin Gallate

Electronically modified, fluorinated catechins and epicatechins are enantioselectively synthesized in a short, convergent sequence via kinetic resolution.

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