Ti-Catalyzed Reductive Dehydroxylative Vinylation of Tertiary Alcohols

ACS Catalysis ◽  
2022 ◽  
pp. 1018-1023
Author(s):  
Hao Xie ◽  
Sheng Wang ◽  
Yuquan Wang ◽  
Peng Guo ◽  
Xing-Zhong Shu
Keyword(s):  
Tertiary Alcohols

Dual Roles of TBHP Enabled Regioselective Hydroetherification of (Trifluoromethyl)alkenes with Boronic Acids: Access to α-Trifluoromethyl β-Aryloxy Tertiary Alcohols

Synthesis ◽  
2021 ◽  
Author(s):  
Hengyuan Li ◽  
Chuanle Zhu
Keyword(s):  
Boronic Acids ◽  
Dual Roles ◽  
Tertiary Alcohols ◽  
High Yields

The three-starting materials four-component reaction of (trifluoromethyl)alkenes, TBHP, and boronic acids is reported, delivering various useful α-trifluoromethyl-β-aryloxy tertiary alcohols in high yields and in an exclusively regioselective hydroetherification manner. TBHP serves as both the oxidants and the nucleophiles in this reaction, as well as the O-source of the products.

Oxidation of chiral α-phenylacetate derivatives: formation of dimers with contiguous quaternary stereocenters versus tertiary alcohols

2005 ◽  
Vol 16 (21) ◽  
pp. 3599-3605 ◽  
Author(s):  
Marisa C. Kozlowski ◽  
Evan S. DiVirgilio ◽  
Krishnan Malolanarasimhan ◽  
Carol A. Mulrooney
Keyword(s):  
Tertiary Alcohols ◽  
Quaternary Stereocenters
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