Kinetics and Energetics of Oxidation of Bitumen in Relation to In Situ Combustion Processes

Author(s):  
Leslie Barta ◽  
Andrew W. Hakin ◽  
Loren G. Hepler
2015 ◽  
Vol 18 (02) ◽  
pp. 158-170 ◽  
Author(s):  
Anna Nissen ◽  
Zhouyuan Zhu ◽  
Anthony Kovscek ◽  
Louis Castanier ◽  
Margot Gerritsen

Summary We demonstrate the effectiveness of a non-Arrhenius kinetic upscaling approach for in-situ-combustion processes, first discussed by Kovscek et al. (2013). Arrhenius reaction terms are replaced with equivalent source terms that are determined by a work flow integrating both laboratory experiments and high-fidelity numerical simulations. The new formulation alleviates both stiffness and grid dependencies of the traditional Arrhenius approach. Consequently, the computational efficiency and robustness of simulations are improved significantly. In this paper, we thoroughly investigate the performance of the non-Arrhenius upscaling method compared with Arrhenius kinetics. We investigate robustness by considering grid effects and sensitivity to heterogeneity. Performance improvements of the new kinetic upscaling approach compared with traditional Arrhenius kinetics are demonstrated through numerical experiments in one and two dimensions for both homogeneous- and heterogeneous-permeability fields.


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