Recent Advances of Photocatalytic Hydrogenation of CO2 to Methanol

Constantly increasing hydrocarbon fuel combustion along with high levels of carbon dioxide emissions has given rise to a global energy crisis and environmental alterations. Photocatalysis is an effective technique for addressing this energy and environmental crisis. Clean and renewable solar energy is a very favourable path for photocatalytic CO2 reduction to value-added products to tackle problems of energy and the environment. The synthesis of various products such as CH4, CH3OH, CO, EtOH, etc., has been expanded through the photocatalytic reduction of CO2. Among these products, methanol is one of the most important and highly versatile chemicals widely used in industry and in day-to-day life. This review emphasizes the recent progress of photocatalytic CO2 hydrogenation to CH3OH. In particular, Metal organic frameworks (MOFs), mixed-metal oxide, carbon, TiO2 and plasmonic-based nanomaterials are discussed for the photocatalytic reduction of CO2 to methanol. Finally, a summary and perspectives on this emerging field are provided.

An Overview of Common Infrared Techniques for Detecting CO Intermediates on Metal Surfaces for Hydrocarbon Products

Detection of intermediates during the catalytic process by infrared techniques has been widely implemented for many important reactions. For the reduction of CO2 into hydrocarbons on metal surfaces, CO molecule is one of the most important transient species to be followed due to its involvement in several products’ pathways, and its distinct vibrational features. Herein, basic understandings behind these utilized infrared techniques are illustrated aiming for highlighting the potential of each infrared technique and its advantages over the other ones for detecting CO molecules on metal surfaces.

An Unprecedented Polyoxometalate-Encapsulated Organo-Metallophosphate Framework as Highly Efficient Cocatalyst for CO2 Photoreduction

The photocatalytic reduction of CO2 to chemical fuels is attractive for addressing both greenhouse effect and energy crisis, but the key challenge is the design and synthesis of photocatalyst with...

Exploring the Adsorption Site Coordination as a Strategy to Tune Copper Catalysts for CO2 Electro-reduction

The electrochemical reduction of CO2 is a promising technology to reach a carbon-neutral economy. However, among other challenges, the design of active and selective catalysts still bottlenecks such advances. Herein,...