Incorporating Transition Metal Complexes into Tetrathioarsenates(V):  Syntheses, Structures, and Properties of Two Unprecedented [Mn(dien)2]n[Mn(dien)AsS4]2n·4nH2O and [Mn(en)3]2[Mn(en)2AsS4][As3S6]

Ming-Lai Fu;  Guo; Li-Zhen Cai;  Zhang; Jin-Shun Huang

doi:10.1021/ic048579f

Incorporating Transition Metal Complexes into Tetrathioarsenates(V): Syntheses, Structures, and Properties of Two Unprecedented [Mn(dien)2]n[Mn(dien)AsS4]2n·4nH2O and [Mn(en)3]2[Mn(en)2AsS4][As3S6]

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Jin-Shun Huang

Keyword(s):

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Metal Complexes ◽

Transition Metal Complexes ◽

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Transition-metal complexes with sulfur ligands. 57. Stabilization of high-valent iron(IV) centers and vacant coordination sites by sulfur .pi.-donation: syntheses, x-ray structures, and properties of [Fe("S2")2(PMe3)n] (n = 1, 2) and (NMe4)[Fe("S2")2(PMe3)2].cntdot.CH3OH ("S2"2- = 1,2-benzenedithiolate(2-))

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Incorporation Transition Metal Complexes into Tetrathioarsenates(V): Syntheses, Structures, and Properties of Two Unprecedented [Mn(dien)2]n[Mn(dien)AsS4]2n×4nH2O and [Mn(en)3]2[Mn(en)2AsS4] [As3S6].

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