“Oxidative Addition” to a Zirconium(IV) Redox-Active Ligand Complex

2005 ◽  
Vol 44 (16) ◽  
pp. 5559-5561 ◽  
Author(s):  
Karen J. Blackmore ◽  
Joseph W. Ziller ◽  
Alan F. Heyduk
Keyword(s):  
Oxidative Addition ◽  
Ligand Complex ◽  
Redox Active Ligand ◽  
Active Ligand ◽  
Redox Active

Catalytic nitrene transfer by a zirconium(iv) redox-active ligand complex

2011 ◽  
Vol 2 (1) ◽  
pp. 166-169 ◽  
Author(s):  
Andy I. Nguyen ◽  
Ryan A. Zarkesh ◽  
David C. Lacy ◽  
Megan K. Thorson ◽  
Alan F. Heyduk
Keyword(s):  
Ligand Complex ◽  
Nitrene Transfer ◽  
Redox Active Ligand ◽  
Active Ligand ◽  
Redox Active

Four-Electron Oxidative Formation of Aryl Diazenes Using a Tantalum Redox-Active Ligand Complex

2008 ◽  
Vol 120 (25) ◽  
pp. 4793-4796 ◽  
Author(s):  
Ryan A. Zarkesh ◽  
Joseph W. Ziller ◽  
Alan F. Heyduk
Keyword(s):  
Ligand Complex ◽  
Redox Active Ligand ◽  
Active Ligand ◽  
Redox Active

Redox-Active Ligand-Assisted Two-Electron Oxidative Addition to Gallium(II)

2018 ◽  
Vol 24 (8) ◽  
pp. 1877-1889 ◽  
Author(s):  
Igor L. Fedushkin ◽  
Vladimir A. Dodonov ◽  
Alexandra A. Skatova ◽  
Vladimir G. Sokolov ◽  
Alexander V. Piskunov ◽  
...  
Keyword(s):  
Oxidative Addition ◽  
Redox Active Ligand ◽  
Active Ligand ◽  
Redox Active

Catalytic Reactivity of a Zirconium(IV) Redox-Active Ligand Complex with 1,2-Diphenylhydrazine

2008 ◽  
Vol 130 (9) ◽  
pp. 2728-2729 ◽  
Author(s):  
Karen J. Blackmore ◽  
Neetu Lal ◽  
Joseph W. Ziller ◽  
Alan F. Heyduk
Keyword(s):  
Ligand Complex ◽  
Redox Active Ligand ◽  
Active Ligand ◽  
Redox Active ◽  
Catalytic Reactivity

Four-Electron Oxidative Formation of Aryl Diazenes Using a Tantalum Redox-Active Ligand Complex

2008 ◽  
Vol 47 (25) ◽  
pp. 4715-4718 ◽  
Author(s):  
Ryan A. Zarkesh ◽  
Joseph W. Ziller ◽  
Alan F. Heyduk
Keyword(s):  
Ligand Complex ◽  
Redox Active Ligand ◽  
Active Ligand ◽  
Redox Active

Reactivity of Aluminum Complexes of Redox-Active Ligand toward N-Heterocyclic Carbene and Its Thione

2019 ◽  
Vol 39 (1) ◽  
pp. 66-73 ◽  
Author(s):  
Vladimir G. Sokolov ◽  
Tatyana S. Koptseva ◽  
Roman V. Rumyantcev ◽  
Xiao-Juan Yang ◽  
Yanxia Zhao ◽  
...  
Keyword(s):  
Redox Active Ligand ◽  
Active Ligand ◽  
Redox Active ◽  
Aluminum Complexes

POSSIBILITY OF MOLECULAR-SWITCH WITH CONTROLLED HYDROGEN BOND: UTILITY OF COMBINATION OF 2,2′-BIIMIDAZOLE AND REDOX-ACTIVE LIGAND

2005 ◽  
Vol 04 (01) ◽  
pp. 333-344 ◽  
Author(s):  
HIROTOSHI MORI ◽  
EISAKU MIYOSHI
Keyword(s):  
Density Functional ◽  
Molecular Level ◽  
Molecular Switch ◽  
Vibration Band ◽  
Functional Theory ◽  
Inorganic Molecule ◽  
Redox Active Ligand ◽  
Active Ligand ◽  
Redox Active ◽  
Stretching Vibration

A new inorganic molecule [ Co(Hbim) ( C 6 H 4 O 2)( NH 3)2]2 that can be used as a new optically durable molecular switch was theoretically designed in the framework of density functional theory. Three stable minima, belonging to 1 A g , 5 A 1, and 9 A g states, were found in the complex. Theoretically predicted infrared spectra of the complexes showed that a strong peak of NH stretching vibration is observed at 2690, 2120, and 2770 cm -1 in the 1 A g , 5 A 1, and 9 A g states, respectively. The apparent red shift of the NH stretching vibration band in the 5 A 1 state make it possible to distinguish the electronic state from others (1 A g and 9 A g ). This means that the complex can be used as a molecular level switch whose memory can be stably read by IR light without any photoreaction process; namely, without memory degradation.

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