Modulation of the Magnetic Properties of Two-Dimensional Compounds [NiX2(N–N)] by Tailoring Their Crystal Structure

2013 ◽  
Vol 52 (12) ◽  
pp. 7087-7093 ◽  
Author(s):  
Miguel Cortijo ◽  
Santiago Herrero ◽  
Reyes Jiménez-Aparicio ◽  
Emilio Matesanz
2016 ◽  
Vol 72 (10) ◽  
pp. 1488-1491
Author(s):  
Fatima Setifi ◽  
Dohyun Moon ◽  
Robeyns Koen ◽  
Zouaoui Setifi ◽  
Morad Lamsayah ◽  
...  

The search for new molecular materials with interesting magnetic properties using the pseudohalide azide ion and quinolin-8-amine (aqin, C9H8N2) as a chelating ligand, led to the synthesis and structure determination of the title complex, [Fe(N3)2(C9H8N2)2]. The complex shows an octahedral geometry, with the FeIIatom surrounded by six N atoms; the two N3−anions coordinate in acisconfiguration, while the remaining N atoms originate from the two quinolin-8-amine ligands with the quinoline N atoms lying on opposite sides of the Fe atom. The crystal packing is dominated by layers of hydrophilic and aromatic regions parallel to theacplane, stabilized by a two-dimensional hydrogen-bonded network and π–π stacking.


Polyhedron ◽  
2009 ◽  
Vol 28 (14) ◽  
pp. 2893-2898 ◽  
Author(s):  
Juraj Černák ◽  
Anna Pavlová ◽  
Alžbeta Orendáčová ◽  
Marcela Kajňaková ◽  
Juraj Kuchár

Polyhedron ◽  
2010 ◽  
Vol 29 (1) ◽  
pp. 188-195 ◽  
Author(s):  
Laura Cañadillas-Delgado ◽  
Oscar Fabelo ◽  
Jorge Pasán ◽  
Miguel Julve ◽  
Francesc Lloret ◽  
...  

2002 ◽  
Vol 55 (4) ◽  
pp. 411-420 ◽  
Author(s):  
Ai-Hua Yuan ◽  
Xiao-Ping Shen ◽  
Qiang-Jin Wu ◽  
Zi-Xiang Huang ◽  
Zheng Xu

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