Crystal structure of bis(azido-κN)bis(quinolin-8-amine-κ2N,N′)iron(II)
2016 ◽
Vol 72
(10)
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pp. 1488-1491
Keyword(s):
The search for new molecular materials with interesting magnetic properties using the pseudohalide azide ion and quinolin-8-amine (aqin, C9H8N2) as a chelating ligand, led to the synthesis and structure determination of the title complex, [Fe(N3)2(C9H8N2)2]. The complex shows an octahedral geometry, with the FeIIatom surrounded by six N atoms; the two N3−anions coordinate in acisconfiguration, while the remaining N atoms originate from the two quinolin-8-amine ligands with the quinoline N atoms lying on opposite sides of the Fe atom. The crystal packing is dominated by layers of hydrophilic and aromatic regions parallel to theacplane, stabilized by a two-dimensional hydrogen-bonded network and π–π stacking.
2016 ◽
Vol 72
(4)
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pp. 470-476
2015 ◽
Vol 71
(3)
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pp. 169-174
2002 ◽
Vol 57
(10)
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pp. 1108-1114
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2007 ◽
Vol 63
(11)
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pp. m2819-m2819
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2015 ◽
Vol 127
(5)
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pp. 849-856
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2015 ◽
Vol 225
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pp. 249-255
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