Structural Control of Copper(I) Coordination Polymers:  Construction of One-, Two-, and Three-Dimensional Frameworks of Tetrahedral Copper(I) Ions Bridged by Dicyanobenzene Derivatives

1997 ◽  
Vol 36 (27) ◽  
pp. 6382-6389 ◽  
Author(s):  
Takayoshi Kuroda-Sowa ◽  
Takashi Horino ◽  
Mikiko Yamamoto ◽  
Yasuhiro Ohno ◽  
Masahiko Maekawa ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Structural Control ◽  
Three Dimensional

Structural control of silver(I) coordination polymers: construction of two- and three-dimensional frameworks of silver(I) ions bridged by dicyanopyrazine derivatives

2000 ◽  
Vol 308 (1-2) ◽  
pp. 17-21 ◽  
Author(s):  
Yusaku Suenaga* ◽  
Toru Kamiya ◽  
Takayoshi Kuroda-Sowa ◽  
Masahiko Maekawa ◽  
Megumu Munakata*
Keyword(s):  
Coordination Polymers ◽  
Structural Control ◽  
Three Dimensional

scholarly journals A New Systematic Construction of Novel Three-Dimensional Spin Crossover Coordination Polymers Based on the [AgI2(CN)3] Building Unit

ACS Omega ◽  
2021 ◽  
Author(s):  
Takashi Kosone ◽  
Syogo Okuda ◽  
Masaya Kawata ◽  
Shunsuke Arai ◽  
Ryota Kosuge ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Spin Crossover ◽  
Three Dimensional ◽  
Systematic Construction ◽  
Building Unit

Highly Ordered Conjugated Polymer Nanoarchitectures with Three-Dimensional Structural Control

Nano Letters ◽  
2009 ◽  
Vol 9 (8) ◽  
pp. 2838-2843 ◽  
Author(s):  
Alexandru Vlad ◽  
Constantin Augustin Dutu ◽  
Pierre Guillet ◽  
Piotr Jedrasik ◽  
Charles-André Fustin ◽  
...  
Keyword(s):  
Conjugated Polymer ◽  
Structural Control ◽  
Three Dimensional

Construction of Co/Ni-based coordination polymers with three-dimensional isostructural frameworks and multiple catalytic applications

2021 ◽  
Vol 296 ◽  
pp. 121979
Author(s):  
Xiuling Zhang ◽  
Yaoqiang Jin ◽  
Guangyin Wang ◽  
Aizhen Liu ◽  
Da-Shuai Zhang ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Three Dimensional ◽  
Catalytic Applications

Three-Dimensional Metal Azide Coordination Polymers with Amino Carboxylate Coligands: Synthesis, Structure, and Magnetic Properties

2009 ◽  
Vol 48 (11) ◽  
pp. 4674-4684 ◽  
Author(s):  
Zi-Lu Chen ◽  
Chun-Fang Jiang ◽  
Wei-Hong Yan ◽  
Fu-Pei Liang ◽  
Stuart R. Batten
Keyword(s):  
Magnetic Properties ◽  
Coordination Polymers ◽  
Three Dimensional ◽  
Metal Azide

Single-Crystal-to-Single-Crystal Transformations of Two Three-Dimensional Coordination Polymers through Regioselective [2+2] Photodimerization Reactions

2010 ◽  
Vol 49 (28) ◽  
pp. 4767-4770 ◽  
Author(s):  
Dong Liu ◽  
Zhi-Gang Ren ◽  
Hong-Xi Li ◽  
Jian-Ping Lang ◽  
Ni-Ya Li ◽  
...  
Keyword(s):  
Single Crystal ◽  
Coordination Polymers ◽  
Three Dimensional

Role of the Auxiliary Ligand in the Spontaneous Resolution of Enantiomers in Three-Dimensional Coordination Polymers

2021 ◽  
Author(s):  
Hui-Jun Chen ◽  
Lu Xu ◽  
Man-Ting Chen ◽  
Li-Rong Lin ◽  
Gui-Lin Zhuang ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Three Dimensional ◽  
Spontaneous Resolution ◽  
Auxiliary Ligand ◽  
Resolution Of Enantiomers

Three-dimensional lanthanide–silver heterometallic coordination polymers: syntheses, structures and properties

CrystEngComm ◽  
2010 ◽  
Vol 12 (10) ◽  
pp. 3267 ◽  
Author(s):  
Man-Sheng Chen ◽  
Zhi Su ◽  
Min Chen ◽  
Shui-Sheng Chen ◽  
Yi-Zhi Li ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Three Dimensional ◽  
Structures And Properties ◽  
Heterometallic Coordination Polymers

scholarly journals Crystal structures of {[Cu(Lpn)2][Fe(CN)5(NO)]·H2O}nand {[Cu(Lpn)2]3[Cr(CN)6]2·5H2O}n[where Lpn = (R)-propane-1,2-diamine]: two heterometallic chiral cyanide-bridged coordination polymers

2015 ◽  
Vol 71 (4) ◽  
pp. 392-397
Author(s):  
Olha Sereda ◽  
Helen Stoeckli-Evans
Keyword(s):  
Hydrogen Bonds ◽  
Coordination Polymers ◽  
Three Dimensional ◽  
Water Molecules ◽  
Two Dimensional ◽  
Asymmetric Unit ◽  
Compound I ◽  
Distorted Octahedral ◽  
Coordination Spheres ◽  
Compound Ii

The title compounds,catena-poly[[[bis[(R)-propane-1,2-diamine-κ2N,N′]copper(II)]-μ-cyanido-κ2N:C-[tris(cyanido-κC)(nitroso-κN)iron(III)]-μ-cyanido-κ2C:N] monohydrate], {[Cu(Lpn)2][Fe(CN)5(NO)]·H2O}n, (I), and poly[[hexa-μ-cyanido-κ12C:N-hexacyanido-κ6C-hexakis[(R)-propane-1,2-diamine-κ2N,N′]dichromium(III)tricopper(II)] pentahydrate], {[Cu(Lpn)2]3[Cr(CN)6]2·5H2O}n, (II) [where Lpn = (R)-propane-1,2-diamine, C3H10N2], are new chiral cyanide-bridged bimetallic coordination polymers. The asymmetric unit of compound (I) is composed of two independent cation–anion units of {[Cu(Lpn)2][Fe(CN)5)(NO)]} and two water molecules. The FeIIIatoms have distorted octahedral geometries, while the CuIIatoms can be considered to be pentacoordinate. In the crystal, however, the units align to form zigzag cyanide-bridged chains propagating along [101]. Hence, the CuIIatoms have distorted octahedral coordination spheres with extremely long semicoordination Cu—N(cyanido) bridging bonds. The chains are linked by O—H...N and N—H...N hydrogen bonds, forming two-dimensional networks parallel to (010), and the networks are linkedviaN—H...O and N—H...N hydrogen bonds, forming a three-dimensional framework. Compound (II) is a two-dimensional cyanide-bridged coordination polymer. The asymmetric unit is composed of two chiral {[Cu(Lpn)2][Cr(CN)6]}−anions bridged by a chiral [Cu(Lpn)2]2+cation and five water molecules of crystallization. Both the CrIIIatoms and the central CuIIatom have distorted octahedral geometries. The coordination spheres of the outer CuIIatoms of the asymmetric unit can be considered to be pentacoordinate. In the crystal, these units are bridged by long semicoordination Cu—N(cyanide) bridging bonds forming a two-dimensional network, hence these CuIIatoms now have distorted octahedral geometries. The networks, which lie parallel to (10-1), are linkedviaO—H...O, O—H...N, N—H...O and N—H...N hydrogen bonds involving all five non-coordinating water molecules, the cyanide N atoms and the NH2groups of the Lpn ligands, forming a three-dimensional framework.

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