Dynamic Liquid Saturation in a Trickle Bed Reactor Involving Newtonian/non-Newtonian Liquid Phase

2009 ◽  
Vol 48 (7) ◽  
pp. 3341-3350 ◽  
Author(s):  
Ajay Bansal ◽  
R. K. Wanchoo ◽  
S. K. Sharma
2021 ◽  
Vol 21 (7) ◽  
pp. 4116-4120
Author(s):  
Seung Kyo Oh ◽  
Huiji Ku ◽  
Gi Bo Han ◽  
Byunghun Jeong ◽  
Young-Kwon Park ◽  
...  

The objective of this study is to evaluate the catalytic performance of pellet-type Ru/γ-Al2O3 as a catalyst during liquid-phase hydrogenation of the aromatic hydrocarbon. The Ru/γ-Al2O3 catalyst was prepared using a wet impregnation method. After adding a binder to Ru/γ-Al2O3, a pellet-type catalyst was obtained through an extrusion method. Nanoporous structures are well developed in the pellet-type Ru/γ-Al2O3 catalyst. The average pore sizes of the Ru/γ-Al2O3 catalysts were approximately 10 nm. The catalytic performance of the pellet-type Ru/γ-Al2O3 catalyst during ethylbenzene hydrogenation was evaluated in a trickle-bed reactor. When the ruthenium loading increased from 1 to 5 wt%, the number of active sites effective for the hydrogenation of ethylbenzene increased proportionally. In order to maximize the conversion of ethylbenzene to ethylcyclohexane, it was necessary to maintain a liquid phase hydrogenation reaction in the trickle bed reactor. In this regards, the reaction temperature should be lower than 90 °C. The conversion of ethylbenzene to ethylcyclohexane on the Ru(5 wt%)/γ-Al2O3 catalyst was highest, which is ascribed to the largest number of active sites of the catalyst.


2007 ◽  
Vol 25 (3) ◽  
pp. 169-181 ◽  
Author(s):  
Venneti M. H. Govindarao ◽  
Karri V. Ramana Murthy

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