Ligand substitution reactions in metal cluster complexes. Evidence for unusually facile metal-metal bond cleavages in the reactions of osmium clusters Os3(CO)11(NCMe) and Os3(CO)10(NCMe)2 with CNCF3 including the isolation and structural characterization of intermediates

Richard D. Adams; Yun Chi; Darryl D. DesMarteau; Dieter Lentz; Robert Marschall; Andreas Scherrmann

doi:10.1021/ja00053a018

Ligand substitution reactions in metal cluster complexes. Evidence for unusually facile metal-metal bond cleavages in the reactions of osmium clusters Os3(CO)11(NCMe) and Os3(CO)10(NCMe)2 with CNCF3 including the isolation and structural characterization of intermediates

Journal of the American Chemical Society ◽

10.1021/ja00053a018 ◽

1992 ◽

Vol 114 (27) ◽

pp. 10822-10826 ◽

Cited By ~ 16

Author(s):

Richard D. Adams ◽

Yun Chi ◽

Darryl D. DesMarteau ◽

Dieter Lentz ◽

Robert Marschall ◽

...

Keyword(s):

Structural Characterization ◽

Metal Cluster ◽

Ligand Substitution ◽

Substitution Reactions ◽

Osmium Clusters ◽

Cluster Complexes ◽

Metal Bond ◽

Metal Metal ◽

Ligand Substitution Reactions

Rhenium Polyhydride Complexes Containing PhP(CH2CH2CH2PCy2)2(Cyttp): Protonation, Insertion, and Ligand Substitution Reactions of ReH5(Cyttp) and Structural Characterization of ReH5(Cyttp) and [ReH4(η2-H2)(Cyttp)]SbF6

Inorganic Chemistry ◽

10.1021/ic9602714 ◽

1996 ◽

Vol 35 (24) ◽

pp. 7166-7173 ◽

Cited By ~ 20

Author(s):

Youhyuk Kim ◽

Haibin Deng ◽

Judith C. Gallucci ◽

Andrew Wojcicki

Keyword(s):

Structural Characterization ◽

Ligand Substitution ◽

Substitution Reactions ◽

Ligand Substitution Reactions

Coordination of Polythioether Macrocycles to Metal Cluster Complexes. 1. The Synthesis and Structural Characterization of Ru5(CO)13(.mu.-.eta.1-12S3)(.mu.5-C) and Ru5(CO)11(.mu.-.eta.3-12S3)(.mu.5-C), 12S3 = 1,5,9-Trithiacyclododecane

Organometallics ◽

10.1021/om00024a032 ◽

1994 ◽

Vol 13 (12) ◽

pp. 4870-4874 ◽

Cited By ~ 5

Author(s):

Richard D. Adams ◽

Stephen B. Falloon ◽

Kenneth T. McBride

Keyword(s):

Structural Characterization ◽

Metal Cluster ◽

Cluster Complexes

Cluster synthesis. 25. Synthesis and characterization of new mixed-metal cluster complexes by metal-metal exchange. Reactions of the sulfido cluster complexes M3(CO)9(.mu.3-CO)(.mu.3-S) (M = iron, ruthenium and osmium) with W(CO)5L (L = CO or PMe2Ph)

Inorganic Chemistry ◽

10.1021/ic00307a005 ◽

1989 ◽

Vol 28 (8) ◽

pp. 1440-1445 ◽

Cited By ~ 20

Author(s):

Richard D. Adams ◽

James E. Babin ◽

Pradeep Mathur ◽

K. Natarajan ◽

Jin Guu Wang

Keyword(s):

Metal Cluster ◽

Synthesis And Characterization ◽

Metal Exchange ◽

Exchange Reactions ◽

Cluster Complexes ◽

Mixed Metal ◽

Metal Metal ◽

Mixed Metal Cluster

ChemInform Abstract: PREPARATION AND STRUCTURAL CHARACTERIZATION OF THE MONO- AND BIS(TRIPHENYLPHOSPHINE)-SUBSTITUTED DERIVATIVES OF CO2(CO)6(μ-AS2). EFFECT OF PHOSPHINE LIGAND SUBSTITUTION ON THE CO2AS2 METAL CLUSTER SYSTEM

Chemischer Informationsdienst ◽

10.1002/chin.198008086 ◽

1980 ◽

Vol 11 (8) ◽

Author(s):

A. S. FOUST ◽

C. F. CAMPANA ◽

J. D. SINCLAIR ◽

L. F. DAHL

Keyword(s):

Structural Characterization ◽

Metal Cluster ◽

Ligand Substitution ◽

Phosphine Ligand ◽

Cluster System ◽

Derivatives Of

ChemInform Abstract: Synthesis and Characterization of (Et4N) (M(CO)5SR) and (Et4N)2(M2(CO)8(SR)2) Complexes (M: Cr, Mo, W). Ligand Substitution Reactions and X-Ray Crystal Structure of (Et4N)2(W2(CO)8(SPh)2).

ChemInform ◽

10.1002/chin.198904251 ◽

1989 ◽

Vol 20 (4) ◽

Author(s):

D. J. DARENSBOURG ◽

K. M. SANCHEZ ◽

J. REIBENSPIES

Keyword(s):

Crystal Structure ◽

Ligand Substitution ◽

Synthesis And Characterization ◽

Substitution Reactions ◽

X Ray ◽

Ligand Substitution Reactions

ChemInform Abstract: REACTIONS OF RE2CL4(DPPM)2 WITH CARBON MONOXIDE THAT PROCEED WITH RETENTION OF THE METAL-METAL BOND: SYNTHESIS OF RE2CL4(DPPM)2(CO)N (N = 1, 2) AND THE STRUCTURAL CHARACTERIZATION OF CL2RE(μ-CL)(μ-CO)(μ-DPPM)2RECL(CO)

Chemischer Informationsdienst ◽

10.1002/chin.198540280 ◽

1985 ◽

Vol 16 (40) ◽

Author(s):

F. A. COTTON ◽

L. M. DANIELS ◽

K. R. DUNBAR ◽

L. R. FALVELLO ◽

S. M. TETRICK ◽

...

Keyword(s):

Carbon Monoxide ◽

Structural Characterization ◽

Metal Bond ◽

Metal Metal

Complex Formation and Ligand Substitution Reactions of (2-Picolylamine)palladium(II) with Various Biologically Relevant Ligands. Characterization of (2-Picolylamine)(1,1-cyclobutanedicarboxylato)palladium(II)

Inorganic Chemistry ◽

10.1021/ic961192v ◽

1997 ◽

Vol 36 (7) ◽

pp. 1454-1463 ◽

Cited By ~ 50

Author(s):

Tobias Rau ◽

Mohamed Shoukry ◽

Rudi van Eldik

Keyword(s):

Complex Formation ◽

Ligand Substitution ◽

Substitution Reactions ◽

Biologically Relevant ◽

Ligand Substitution Reactions

Synthesis and structural characterization of bis[bis(dimethylphenylphosphine)dichlororhenium](n+) ion (n = 0-2): a series of complexes processing metal-metal bond orders of 4, 3.5, and 3 and the dependence of bond length upon bond order

Journal of the American Chemical Society ◽

10.1021/ja00353a018 ◽

1983 ◽

Vol 105 (15) ◽

pp. 4950-4954 ◽

Cited By ~ 46

Author(s):

F. Albert Cotton ◽

Kim R. Dunbar ◽

Larry R. Falvello ◽

Milagros Tomas ◽

Richard A. Walton

Keyword(s):

Bond Length ◽

Structural Characterization ◽

Bond Order ◽

Bond Orders ◽

Metal Bond ◽

Metal Metal

ChemInform Abstract: Cluster Synthesis. Part 25. Synthesis and Characterization of New Mixed-Metal Cluster Complexes by Metal-Metal Exchange. Reactions of the Sulfido Cluster Complexes M3(CO)9(μ3-CO)(μ3-S) (M: Fe, Ru, and Os) with W(CO)5L (L: CO or PMe2Ph

ChemInform ◽

10.1002/chin.198931262 ◽

1989 ◽

Vol 20 (31) ◽

Author(s):

R. D. ADAMS ◽

J. E. BABIN ◽

P. MATHUR ◽

K. NATARAJAN ◽

J.-G. WANG

Keyword(s):

Metal Cluster ◽

Synthesis And Characterization ◽

Metal Exchange ◽

Exchange Reactions ◽

Cluster Complexes ◽

Mixed Metal ◽

Metal Metal ◽

Mixed Metal Cluster

Synthesis of square-pyramidal platinum-osmium clusters by metal-metal exchange. Isolation and structural characterization of a hexanuclear intermediate

Inorganic Chemistry ◽

10.1021/ic00221a003 ◽

1986 ◽

Vol 25 (1) ◽

pp. 4-5 ◽

Cited By ~ 9

Author(s):

Richard D. Adams ◽

James E. Babin ◽

Rahina Mahtab ◽

Suning Wang

Keyword(s):

Structural Characterization ◽

Metal Exchange ◽

Osmium Clusters ◽

Metal Metal