A Lewis acid-mediated version of the Nicholas reaction: Synthesis of syn-alkylated products and cobalt-complexed cycloalkynes

1986 ◽  
Vol 108 (11) ◽  
pp. 3128-3130 ◽  
Author(s):  
Stuart L. Schreiber ◽  
Tarek. Sammakia ◽  
William E. Crowe
2008 ◽  
Vol 49 (48) ◽  
pp. 6768-6772 ◽  
Author(s):  
Palakodety Radha Krishna ◽  
Empati Raja Sekhar ◽  
Florence Mongin

2016 ◽  
Vol 7 (1) ◽  
pp. 394-399 ◽  
Author(s):  
Wafa Gati ◽  
Hisashi Yamamoto

“Super silyl” governed diastereoselective Mukaiyama aldol reaction for the construction of protected α,β-dioxyaldehydes and 1,2,3-triols via Lewis acid catalysis.


2012 ◽  
Vol 2012 (31) ◽  
pp. 6236-6247 ◽  
Author(s):  
Guoqing Zhao ◽  
Binjie Wang ◽  
Weijun Yang ◽  
Hongjun Ren

Synlett ◽  
2017 ◽  
Vol 28 (20) ◽  
pp. 2923-2927 ◽  
Author(s):  
Brent Onge ◽  
James Green

The Lewis acid mediated Nicholas reaction of potassium alkynyltrifluoroborates and propargyl acetate-hexacarbonyldicobalt complexes affords 1,4-diyne dicobalt hexacarbonyl complexes in good yields. The analogous Nicholas reactions of potassium alkenyltrifluoro­borates give 1,3-enyne dicobalt hexacarbonyl complexes in most cases, although the initial site of reaction can vary. Potassium vinyltrifluoroborate itself affords alkynylcyclopropane complexes.


ChemInform ◽  
2013 ◽  
Vol 44 (12) ◽  
pp. no-no
Author(s):  
Guoqing Zhao ◽  
Binjie Wang ◽  
Weijun Yang ◽  
Hongjun Ren

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