One-step catalytic upgrading of bio-based furfural to γ-valerolactone actuated by coordination organophosphate-Hf polymers

Coordination polymers are closely correlated with porous and robust structures. In this work, a variety of novel coordination organophosphate-Hf polymers functionalized with Brønsted/ Lewis acid and base sites were prepared...

Lewis acid / Base-free Strategy for the Synthesis of 2-Arylthio and Selenyl Benzothiazole / Thiazole and Imidazole

A Cu(II)-catalyzed Csp2-Se and Csp2-Sulfur bond formation was achieved with moderate to good yields without the aid of Lewis acid and base. The reaction is compatible with a wide range of heterocycles such as benzothiazole, thiazole, and imidazole. Also, this typical protocol is found to be active in thio-selenation via S-H activation. Additionally, we proposed a plausible mechanistic pathway involving Cu(III) putative intermediate.

Base-promoted Lewis acid catalyzed synthesis of quinazoline derivatives

A one-pot protocol has been developed for the synthesis of quinazolinones from amide-oxazolines with TsCl via a cyclic 1,3-azaoxonium intermediate and 6π electron cyclization in the presence of a Lewis acid and base.

Highly efficient synergistic CO2 conversion with epoxide using copper polyhedron-based MOFs with Lewis acid and base sites

The catalytic performances and effect of LASs and LBSs of four isomorphous Cu-PMOFs in CO2 cycloaddition reaction were systematically studied. JLU-Liu21 exhibited significant catalytic efficiency, remarkable recyclability and catalytic stability.

Synergetic effect of Lewis acid and base in modified Sn-β on the direct conversion of levoglucosan to lactic acid

The synergetic effect of Lewis acid and base in modified Sn-β boosts the yield of lactic acid produced from levoglucosan.

Synergistic visible light photoredox catalysis

Within the last decade the combination of photoredox catalysis and other catalytic modes of activation has become a powerful tool for organic synthesis to enable transformations that are not possible using single catalyst systems and hence are complementary to traditional methodology. Especially reactions proceeding via synergistic catalysis where co-catalyst and photocatalyst simultaneously and separately activate different reaction partners greatly benefit from the special properties of molecules and transition metal complexes in their excited state being oxidizing and reducing in nature at the same time. Apart from allowing for the generation of radical (open-shell) reactive intermediates by SET under mild conditions from bench-stable, abundant precursors, the photocatalyst often acts to interweave the distinct catalytic cycles by interaction at multiple points of the reaction mechanism to provide overall redox-neutral processes by shuttling electrons within in this complex network of elementary reaction steps. Synergistic strategies moreover may allow to performing such reactions with enantioselectivity, while mostly the selectivity is achieved by the chiral co-catalyst. The merger of photocatalysis has been achieved with a broad range of alternative modes of catalysis including organocatalysis, Brønstedt and Lewis acid and base catalysis, enzyme catalysis as well as in the context of cross-coupling transition metal catalysis overcoming challenging steps in this methodology and therefore has contributed to considerably expand the repertoire of suitable coupling partners. While only selected examples will be discussed, this chapter will highlight various dual catalytic platforms focusing on the photocatalytically generated intermediates, but also illustrating the diverse roles of photocatalysts in the context of such synergistic multicatalysis reactions.